To save content items to your account,
please confirm that you agree to abide by our usage policies.
If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account.
Find out more about saving content to .
To save content items to your Kindle, first ensure no-reply@cambridge.org
is added to your Approved Personal Document E-mail List under your Personal Document Settings
on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part
of your Kindle email address below.
Find out more about saving to your Kindle.
Note you can select to save to either the @free.kindle.com or @kindle.com variations.
‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi.
‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.
Beltrami's discovery that corresponding to any ruled surface there is another applicable on it having corresponding generators parallel but with the parameter of distribution of opposite signs, has brought into prominence the distinction between the applicability of two surfaces and the continuous deformation of one into the other. It is pointed out that since the parameter of distribution differs in sign, the tangent plane rotates in opposite directions as the point of contact proceeds along the two corresponding generators on the respective surfaces. One surface cannot, therefore, be deformed into the other. It is proposed in the present paper to investigate the distinction between applicability and deformability of two surfaces in general, and to connect this isolated fact with the general theory of deformation.
When an atomic system emits or absorbs radiation, the frequency of the radiation is connected with the change of energy of the system by Bohr's frequency condition δE = hv. This equation is usually applied to the transition of an atom from one stationary state to another, the frequency of the radiation being measured in a frame of reference in which the atom as a whole is at rest, both before and after the transition. It has been pointed out by Bohr that difficulties arise when no natural frame of reference presents itself in which to measure the frequency, which is the case for non-isolated systems, or even for isolated systems when the process of radiation is connected with a change of momentum.
In two recent papers in the Philosophical Magazine the statistical theory of collisions of electrons with atoms has been considered, and applied to explain the observed features of the capture and loss of electrons by α-particles. The basis of that discussion can however be improved. Firstly, interactions with the core of any atom entered by the α-particle were explicitly ignored. Such interactions—or rather interactions with the general intra-atomic field as distinct from individual electrons—might be expected to be (and are) important, and it has been found possible to include them in this paper. Secondly, the frequency laws for the processes concerned were based on the classical Thomson-Bohr theory of ionization by collision. This theory—it is well known—does not completely reproduce experimental facts at α-particle velocities, and a less restrictive form can be given to the frequency laws which appears to be in accord with all the known facts. The application to the capture and loss of electrons by α-particles proves to be unaffected.
In hypergeometry loci defined by parametric equations
have been frequently discussed from various points of view. Among other properties these loci possess two systems of generating spaces obtained by keeping the α's (or β's) fixed while the β's (or α's) vary, the simplest example being the generators of a quadric in S3. Another method of obtaining loci having these properties is by taking the flat spaces through the sets of a linear series of sets of points on an elliptic curve and the flat spaces through the sets of the residual series (the curve being supposed normal. In this way we shall obtain a configuration of ∞PSP's and ∞qSq's, the dual of which gives a locus included among those represented by (1).
It is possible to obtain approximate theoretical relations between the spectra of different atoms ionised to such an extent that they possess the same electron structure. In this paper these relations are used to extrapolate values of the terms of the spectra of various lithium-like and sodium-like atoms.
From the terms so estimated lines can be calculated, and in many cases correlated with lines observed by Millikan and Bowen in the hot spark spectrum of the corresponding element. Revised term values can then be calculated from the lines so identified.
The spectra of lithium-like atoms treated in this way include those from Be II up to O VI, and those of sodium-like atoms, the spectra P V and S VI.
Let N (T) denote, as usual, the number of zeros of ζ (s) whose imaginary part γ satisfies 0 < γ < T, and N (σ, T) the number of these for which, in addition, the real part is greater than σ. In this definition we suppose, in the first place, that no zero actually lies on the line t = T: if the line contains zeros we define
In all methods of measuring excitation and ionisation potentials which are in common use the current-voltage characteristic curves of the apparatus are plotted. In the absence of gas these curves are smooth, but on the admission of gas at a suitable pressure sharp upward bends occur at definite voltages, which are interpreted as the critical potentials of the gas. In a variation by Franck and Hertz, the so-called inelastic impact method, these bends are downward, the critical points being represented by maxima.
In addition to the simple thallous and thallic chlorides and bromides, a considerable number of intermediate and mixed halides have been described by various investigators. Most of the modern work on these substances has been done by Thomas, by Meyer and by Cushman. There is general agreement as regards the existence of substances of the type TlX3. 3TlX, but considerable divergence exists with regard to the mixed chlorobromides. Compounds of the type TlX3. TlX have also been described, the best known of which appears to be the dibromide TlBr3. TlBr.
The results of the present paper were developed some years ago for quite trivial purposes. It seems possible, however, to judge by a recent publication, that they may sooner or later have scientific utility. They have also a certain slight intrinsic interest.
The problem of finding general types of solution for the steady flow of gases in two dimensions, adiabatically and without friction, does not appear to have received a great deal of attention. An interesting and suggestive treatment of hydrodynamics applied to gases is given in Riemann-Weber's Partielle Differential-Gleichungen, but the application is to pressure propagation. Reference must also be made to a paper by the late Lord Rayleigh, who gave a general differential equation which must be satisfied by the velocity potential ø, but the problem of utilizing this equation does not appear easy.
§ 1. In the transformation corresponding to constant acceleration, and in the resulting quadratic form, there is an arbitrary constant. In Einstein's formula for central acceleration a mass m defining the acceleration appears, but no arbitrary constant. In seeking to account for, or to repair, the deficiency I retained all constants naturally arising in the integration of the differential equations, and it then appeared that the result could be obtained by transformation. It will be convenient to state the transformation at the outset, and then to examine the differential equations with a view to a clear understanding of the assumptions made in reaching the more general result.
1. Changes in the relative intensities of the lines in the fluorescent L-spectrum of Cerium excited by radiation of various wave-lengths have been observed.
2. These results imply a change in the relative absorbing powers of the three L-levels as the wave-length of the absorbed radiation diminishes from a value just below the absorption wave-length of the L-levels to a value considerably below. The absorbing power of the LI-level becomes increased relative to the absorbing powers of the other L-levels as the wave-length diminishes. The results agree with those published by H. Robinson in a recent paper.
3. These results imply a breakdown of the law that μ/λ3 is a constant (where μ is the absorption coefficient of X-rays of wave-length λ) as applied to the individual L-levels of an element.
4. A comparison is made between the above results, and some results on the relative absorbing process of the L-levels obtained by Ellis and Skinner from β-ray spectra.
On certain assumptions as to the quantum numbers of the normal orbits of the successive electrons captured by an atom, the successive ionisation potentials can be estimated by making use of the relations between terms of the same quantum number for different atoms of the same electronic structure. Formulae for several of the successive ionisation potentials are given, the form of the formulae being suggested by theoretical reasoning and numerical values of the constants determined from known spectra; the successive ionisation potentials of O, Fe and Ag, calculated from these formulae, are tabulated. It is pointed out how far different these ionisation potentials are from the X-ray excitation potential of the same orbit of a neutral atom.
A complex or system ∞3 of conics in space of four dimensions is such that a finite number of conics pass through an arbitrary point. Linear complexes are those for which this number is unity, and are such that their curves are defined by conditions of incidence with fixed surfaces, curves and points. In this paper are discussed briefly the linear complexes defined by the condition that their curves meet an irreducible curve in four points. Denoting by a curve of order m and genus p it is found that the curves in question are The complex associated with is considered in greater detail, since it is found to have an interesting connection with the well-known Weddle quartic surface of ordinary space. In fact the conics of the system touching a space (of three dimensions) do so in the points of such a surface. The main properties of this surface can be thence deduced. In addition we discuss certain results in connection with this curve . The paper closes with certain enumerative results which were obtained in the course of the researches giving the results recorded and which we believe are worth record.
The object of the present communication is to give an account of an investigation of the problem of four particles on the lines of my investigation of the problem of three particles, an account of which has been recently published by the Society.
The connexion between the conditions for five lines of S4
(i) to lie upon a quadric threefold,
and (ii) to be chords of a normal quartic curve,
leads to an apparent contradiction. This difficulty is explained in the first paragraph below and, subsequently, two investigations are given of which the first uses, mainly, properties of space of three dimensions.