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Solidification of droplets is of great importance to various technological applications, drawing considerable attention from scientists aiming to unravel the fundamental physical mechanisms. In the case of multicomponent droplets undergoing solidification, the emergence of concentration gradients may trigger significant interfacial flows that dominate the freezing dynamics. Here, we experimentally investigate the fascinating interfacial freezing dynamics of supercooled ethanol–water droplets, accompanied with the migration and growth of massive ice particles. We reveal that this unique freezing dynamics is driven by solidification-induced solutal Marangoni flow within the droplets. Our model, which incorporates the temperature- and concentration-dependent properties of the ethanol–water mixture, quantitatively predicts both the migration velocity and the growth rate of the ice particles. The former is determined by the solutal Marangoni flow velocity, while the latter is governed by a balance between the latent heat release and the enhanced thermal dissipation by the Marangoni flow. Moreover, we show that the final wrapping state of droplets can be modulated by the concentration of ethanol. Our findings may pave the way for novel insights into the physicochemical hydrodynamics of multicomponent liquids undergoing phase transitions.
For decades, it has been established that there are two distinct types of instability waves leading to rotating stall in compressors, known as modes and spikes. Modal-type stall inception can be explained by conventional stability theory; however, spike-type instabilities are inherently nonlinear, whose exploration requires a different theoretical approach. For this problem, a two-dimensional point vortex instability model is developed in this paper. This simple model represents a cascade of blades by a row of bound vortices and large-scale shed vortices by point vortices. It assumes that lift on an overloaded blade abruptly drops as local incidence exceeds a critical value, analogous to leading edge stall of an isolated aerofoil, such that local cascade characteristic can be expressed as a discontinuous function. The nonlinearity thus introduced precludes the possibility of modal-type inception. As the results show, a localised stall cell will be formed in the cascade once a local perturbation triggers a discontinuous drop in blade loading, which is bounded by the stall and starting vortices shed respectively from the stalling and unstalling blades. Accordingly, a spike appears in the calculated velocity or pressure trace, directly growing into rotating stall. With this model, the experimentally observed features of spike stall are qualitatively reproduced. Moreover, the temporal variation of the stall cell size is predicted for the first time, showing qualitative agreement with existing experiments. Finally, a new prediction is made that the spike amplitude increases approximately linearly with time, in contrast to the exponential growth of linear modes.
We introduce a novel experimental approach for measuring Onsager coefficients in steady-state multiphase flow through porous media, leveraging the fluctuation–dissipation theorem to analyse saturation fluctuations. This method provides a new tool for probing transport properties in porous media, which could aid in the characterisation of key macroscopic coefficients such as relative permeability. The experimental set-up consists of a steady-state flow system in which two incompressible fluids are simultaneously injected into a modified Hele-Shaw cell, allowing direct visualisation of the dynamics through optical imaging. By computing the temporal correlations of saturation fluctuations, we extract Onsager coefficients that govern the coupling between phase fluxes. Additionally, we have performed a statistical analysis of the fluctuations in the derivative of saturation under different flow conditions. This analysis reveals that while the fluctuations follow Gaussian statistics up to 2–3 standard deviations, they exhibit heavy tails beyond this range. This work provides an experimental foundation for recent theoretical developments in the extention of non-equilibrium thermodynamics to multiphase porous media flows. By linking microscopic fluctuations to macroscopic transport behaviour, our approach offers a new perspective that may complement existing techniques in the study of multiphase flow, making it relevant to both statistical physics and the broader fluid mechanics community.
The objective of this work is to investigate the unexplored laminar-to-turbulent transition of a heated flat-plate boundary layer with a fluid at supercritical pressure. Two temperature ranges are considered: a subcritical case, where the fluid remains entirely in the liquid-like regime, and a transcritical case, where the pseudo-critical (Widom) line is crossed and pseudo-boiling occurs. Fully compressible direct numerical simulations are used to study (i) the linear and nonlinear instabilities, (ii) the breakdown to turbulence, and (iii) the fully developed turbulent boundary layer. In the transcritical regime, two-dimensional forcing generates not only a train of billow-like structures around the Widom line, resembling Kelvin–Helmholtz instability, but also near-wall travelling regions of flow reversal. These spanwise-oriented billows dominate the early nonlinear stage. When high-amplitude subharmonic three-dimensional forcing is applied, staggered $\Lambda$-vortices emerge more abruptly than in the subcritical case. However, unlike the classic H-type breakdown under zero pressure gradient observed in ideal-gas and subcritical regimes, the H-type breakdown is triggered by strong shear layers caused by flow reversals – similar to that observed in adverse pressure gradient boundary layers. Without oblique wave forcing, transition is only slightly delayed and follows a naturally selected fundamental breakdown (K-type) scenario. Hence in the transcritical regime, it is possible to trigger nonlinearities and achieve transition to turbulence relatively early using only a single two-dimensional wave that strongly amplifies background noise. In the fully turbulent region, we demonstrate that variable-property scaling accurately predicts turbulent skin-friction and heat-transfer coefficients.
The present work aims at exploring the scale-by-scale kinetic energy exchanges in multiphase turbulence. For this purpose, we derive the Kármán–Howarth–Monin equation which accounts for the variations of density and viscosity across the two phases together with the effect of surface tension. We consider both conventional and phase conditional averaging operators. This framework is applied to numerical data from detailed simulations of forced homogeneous and isotropic turbulence covering different values for the liquid volume fraction, the liquid–gas density ratio, the Reynolds number and the Weber number. We confirm the existence of an additional transfer term due to surface tension. Part of the kinetic energy injected at large scales is transferred into kinetic energy at smaller scales by classical nonlinear transport while another part is transferred to surface energy before being released back into kinetic energy, but at smaller scales. The overall kinetic energy transfer rate is larger than in single-phase flows. Kinetic energy budgets conditioned in a given phase show that the scale-by-scale transport of turbulent kinetic energy due to pressure is a gain (loss) of kinetic energy for the lighter (heavier) phase. Its contribution can be dominant when the gas volume fraction becomes small or when the density ratio increases. Building on previous work, we hypothesise the existence of a pivotal scale above which kinetic energy is stored into surface deformation and below which the kinetic energy is released by interface restoration. Some phenomenological predictions for this scale are discussed.
Phenotypic plasticity refers to the capacity of an organism’s phenotype to vary in response to changes in environmental conditions, without any change in the individual genotype. Sea urchins (Echinoidea) are well-known for their morphological and behavioural plasticity in response to changing habitats or trophic environments. Phenotypic plasticity has been little studied in directly developing species, in which low levels of phenotypic plasticity are usually expected as a consequence of high levels of genetic differentiation among populations and local genetic adaptation. In the present work, we report a significant plasticity in the direct-developing and brooding sub-Antarctic species Ctenocidaris (Eurocidaris) nutrix (Echinoidea, Cidaridae) through morphological and trophic analyses of gut contents and δ13C and δ15N isotopic compositions. Molecular data (COI mtDNA) confirm that the different phenotypes of C. nutrix, the short-spined C. nutrix nutrix and the long-spined C. nutrix longispina, are a single species restricted to sub-Antarctic waters. As formerly demonstrated in broadcasting echinoid species, morphological plasticity appears to be mainly linked to depth and swell exposure, specimens from exposed and shallow sites showing shorter spines and larger apical systems compared to specimens from sheltered or deep sites. Significant differences in the diet and trophic niche of the different phenotypes suggest that prey type and food diversity may also be a factor promoting distinct phenotypic responses, both in the feeding behaviour and morphology of echinoids.
The linear Faraday instability of a viscous liquid film on a vibrating substrate is analysed. The importance is in the first step in applications for ultrasonic liquid-film destabilisation. The equations of motion are linearised and solved for a liquid film with constant thickness vibrating in a direction normal to its interface with an ambient gaseous medium treated as dynamically inert. Motivated by empirical evidence and the weakly nonlinear analysis of Miles (J. Fluid Mech., vol. 248, 1993, pp. 671–683), we choose an ansatz that the free liquid-film surface forms a square-wave pattern with the same wavenumbers in the two horizontal directions. The result of the stability analysis is a complex rate factor in the time dependency of the film surface deformation caused by the vibrations at a given excitation frequency and vibration amplitude. The analysis allows Hopf bifurcations in the liquid-film behaviour to be identified. Regimes of the deformation wavenumber and the vibration amplitude characterised by unstable film behaviour are found. Inside the regimes, states with given values of the deformation growth rate are identified. The influence of all the governing parameters, such as the vibration amplitude and frequency, the deformation wavenumber and the liquid material properties, on the liquid-film stability is quantified. Non-dimensional relations for vibration amplitudes characteristic for changing stability behaviour are presented.
The bulk organic-matter content of near-surface sediment is widely used for radiocarbon (14C) dating, despite often containing organic carbon (OC) older than the depositional age. Low-temperature combustion can mitigate the influence of old OC, producing ages closer to the depositional age. We developed a simple method to determine the 14C age of the low-temperature (<250°C) component of bulk sediment. Sediment samples from five Arctic lakes were heated up to 400°C, revealing that at 250°C, about half of the OC combusts, leaving behind the more recalcitrant fraction. We applied this method to 64 samples from late glacial and Holocene sediment cores, analyzing 14C and % OC in two aliquots: one heated at 250°C and one unheated. The low-temperature 14C age was calculated by difference using a two-component mixing model. Accuracy was assessed by comparing ages with macrofossils from 48 samples, and reproducibility was tested using a standard reference material. Results show that low-temperature combustion yields 14C ages with an interquartile range of 115 years, and with reproducibility on par with that of macrofossil dating. On average, the ages differ by 932 years from macrofossils, compared to a 2425-year difference for conventional bulk-sediment ages analyzed in this study. Accuracy improves for samples where the proportion of residual OC after heating is low. This practical and efficient method complements macrofossil dating, supports analysis of a large number of samples, and provides insights into sedimentary carbon cycling.
Antiquities in the Middle East region face various threats, including illicit trade, theft, and forgery. This research examines a leather manuscript obtained by the Palestinian Tourist Police following the arrest of an antiquities smuggler. The manuscript contains Phoenician inscriptions along with symbols such as the Menorah, Shofar, and a plant branch. Radiocarbon dating using accelerator mass spectrometry (AMS) techniques determined the manuscript’s date to be post-1950 CE. Therefore, the results indicate that the manuscript is a modern forgery, likely created for commercial purposes. Additionally, the text contains several grammatical errors, further supporting the conclusion that it is not an authentic historical artifact.
The turbulent evolution of the shallow water system exhibits asymmetry in vorticity. This emergent phenomenon can be classified as ‘balanced’, that is, it is not due to the inertial-gravity-wave modes. The quasi-geostrophic (QG) system, the canonical model for balanced motion, has a symmetric evolution of vorticity, thus misses this phenomenon. Here, we present a next-order-in-Rossby extension of QG, $\textrm {QG}^{+1}$, in the shallow water context. We recapitulate the derivation of the model in one-layer shallow water grounded in physical principles and provide a new formulation using ‘potentials’. Then, the multi-layer extension of the shallow water quasi-geostrophic equation ($\textrm {SWQG}^{+1}$) model is formulated for the first time. The $\textrm {SWQG}^{+1}$ system is still balanced in the sense that there is only one prognostic variable, potential vorticity (PV), and all other variables are diagnosed from PV. It filters out inertial-gravity waves by design. This feature is attractive for modelling the dynamics of balanced motions that dominate transport in geophysical systems. The diagnostic relations connect ageostrophic physical variables and extend the massively useful geostrophic balance. Simulations of these systems in classical set-ups provide evidence that $\textrm {SWQG}^{+1}$ captures the vorticity asymmetry in the shallow water system. Simulations of freely decaying turbulence in one layer show that $\textrm {SWQG}^{+1}$ can capture the negatively skewed vorticity, and simulations of the nonlinear evolution of a baroclinically unstable jet show that it can capture vorticity asymmetry and finite divergence of strain-driven fronts.
Our group has previously characterised a post-violet infrared stimulated luminescence (pVIRSL) signal and developed a post-violet infrared single-aliquot regenerative-dose (pVIR-SAR) protocol for estimation of paleodoses. The protocol provides an opportunity for measuring polymineral samples as violet stimulation prior to IRSL measurement, bleaches natural luminescence signal of quartz, and makes it possible to probe photo-transferred charges in feldspar through IR stimulation. This study presents the results of the pVIR-SAR protocol on natural polymineral fine- (4–11 μm) and coarse-grain (90–150 μm) samples, including volcanic ash, pottery, and fluvial deposits from varied geological provenances. The results show that pVIR-SAR ages of both these fine- and coarse-grain samples are consistent with geological reasoning and available age controls thereby suggest that with the use of the pVIR-SAR protocol, mineral separation can be dispensed. This study also reports on the bleachability, athermal fading rates, and alpha efficiencies of pVIRSL for these samples and corresponding results are compared with IRSL at 50°C and post-IR IRSL (pIRIRSL) at 290°C. The pVIRSL signal has a better bleachability and reproducibility compared to the pIRIRSL signal. For the fluvial deposits dated in this study, the fine-grain samples provide ages consistent with the expected chronology.
This study presents a comparative analysis of the radiocarbon dates obtained on paired samples of various organic materials extracted from a lake sediment core. AMS radiocarbon dating of bulk sediment, chironomid capsules, and Trapa seeds was conducted to assess whether systematic offsets exist in the dates obtained on material that are commonly used to develop chronological frameworks for lake-based paleoenvironmental research. The findings reveal significant discrepancies between 14C dates obtained on bulk sediment, chironomid capsules, and on the Trapa seeds used to develop a previously published age-depth model for a sediment core recovered from Deoria Tal, Garhwal Himalaya, India. The systematic offset between the bulk sediment, and to a lesser extent chironomid remains, and the Trapa seeds is attributed to the integration of allochthonous carbon in the bulk sediment, leading to older apparent ages. The 3.6‰ shift in the δ13C value of the bulk sediment at 252 cm is inferred to reflect an increase in the contribution of C4 plant matter to the lake. The increase in enriched δ13C organic matter, coincident with the increasing offset between the dates obtained on bulk sediment and chironomids, and those obtained on the Trapa seeds, between 800 and 400 cal BP, was likely driven by anthropogenic land use changes, as evidenced by the four-fold increase in Cerealia-type pollen during this interval. This study underscores the necessity of selecting appropriate materials for radiocarbon dating to ensure accurate chronological reconstruction and highlights the potential of using chironomids remains to develop robust radiocarbon chronologies for lake sediment records.
Quantifying marine reservoir effects (MREs) across time and space is crucial for establishing accurate archaeological chronologies, including the activities of past hominines. Although the northern Iberian Peninsula shows a high density of Upper Paleolithic sites and marine shells are frequently found in these assemblages, quantification of MREs in this coastal region remains limited. We performed Bayesian modeling of radiocarbon measurements from both terrestrial (Capra pyrenaica, Cervus elaphus and other herbivores unidentified at species level) and marine (Littorina littorea Linnaeus, 1758 and Patella vulgata Linnaeus, 1758 taxa) archaeological samples recovered from the Tito Bustillo cave (Asturias, Spain) in order to determine the ΔR values for northern Iberia during the Lower Magdalenian period (ca. 20–17 ka cal BP). For the time span between 18.6 and 18.2 ka cal BP we estimated ΔR values of –298±44 14C yr and –495±122 14C yr for the periwinkle L. littorea and the common limpet P. vulgata, respectively. This finding has significant implications for future archaeological research in the northern Iberian Peninsula, as researchers must apply distinct ΔR values depending on the mollusk species selected for radiocarbon dating. Furthermore, the consistency between our calculated ΔR value for P. vulgata and previously recorded data for the same taxon from a neighboring coastal region (Cantabria, Spain) suggests remarkable stability in the marine environment of this area during the Lower Magdalenian period.
The interaction between cavitation bubbles and particles near rigid boundaries plays a crucial role in applications from surface cleaning to cavitation erosion. We present a combined experimental, numerical and theoretical investigation of how boundary layer flows affect particle motion during the growth and collapse of the cavitation bubble. Using laser-induced cavitation bubbles and particles of varying radius ratios and stand-off distances, we observe that increasing the bubble-to-particle size ratio suppresses particle displacement. Through one-way coupled simulations and theoretical modelling, we demonstrate that this suppression arises from a shift in the dominant forces acting on the particle: for small radius ratios, the pressure gradient force governs particle motion, while for large ratios, the interplay between added mass, lubrication, and pressure gradient forces becomes significant due to boundary layer growth in the bubble-induced stagnation flow. Based on a theoretical framework combining potential flow theory and axisymmetric viscous stagnation flow analysis, we identify the inviscid- and viscous-flow dominated regimes characterised by the combination of the stand-off distance, the bubble-to-particle radius ratio, and the bubble Reynolds number. Finally, we derive scaling laws for particle displacement consistent with experiments and simulations. These findings advance our understanding of unsteady boundary layer effects in cavitation bubble-particle interactions, offering new insights for applications in microparticle manipulation and flow measurements.