Although there is substantial literature demonstrating evidence of a positive association between volunteerism and well-being, this relationship is under-explored among specific types of volunteerism, including in child welfare roles. This cross-sectional quantitative study used a sample of 302 volunteers in the role of “Host Families” from Safe Families for Children to explore whether six dimensions of well-being are associated with volunteering in child welfare or any specific type of motivation. Results demonstrate mixed evidence of significant associations between volunteering, well-being, and motivation. However, the results show there is no apparent decrease in the well-being of the child welfare volunteers. Rather, they are healthy, happy, and satisfied with life despite the cultural belief that child welfare work is distressing. Additionally, this study offers reliable options for operationalizing well-being and motivation. This may promote improved opportunities for accurate comparisons between future studies investigating volunteerism.