In this chapter, we present some fundamental issues about approximation methods that are often used when a quantum-mechanical system is perturbed and about the relationship between classical and quantum mechanics. In Sec. 10.1 we introduce the stationary perturbation theory, while Sec. 10.2 is devoted to time-dependent perturbations. In Sec. 10.3 we briefly examine the adiabatic theorem. In Sec. 10.4 we introduce the variation method, an approximation method that is not based on perturbation theory. In Sec. 10.5 we discuss the classical limit of the quantum-mechanical equations, whereas in Sec. 10.6 we deal with the semiclassical approximation, in particular the WKB method. On the basis of the previous approximation methods in Sec. 10.7 we present scattering theory. Finally, in Sec. 10.8 we treat a method that has a wide range of applications: the path-integral method.

Stationary perturbation theory

Perturbation theory is a rather general approximation method that may be applied when a small additional force (the perturbation) acts on a system (the unperturbed system), whose quantum dynamics is fully known. If the disturbance is small, it modifies both the energy levels and the stationary states. This allows us to make an expansion in power series of a perturbation parameter, which is assumed to be small. Perturbation theory may be applied both to the case where the additional force is time-independent (in which case a stationary treatment suffices – the subject of the present section) as well as to the case where it explicitly depends on time.

In this chapter we shall discuss some elementary examples of quantum dynamics. In Sec. 4.1 we shall go back to the problem of a particle in a box, this time with finite potential wells. In Sec. 4.2 we shall analyze the effects of a potential barrier on a moving particle. In Sec. 4.3 we shall consider another quantum effect which has no analogue in the classical domain: a quantum particle can tunnel in a classically forbidden region. In Sec. 4.4 perhaps the most important dynamical typology (with a wide range of applications) is considered: the harmonic oscillator. Finally, in Sec. 4.5 several types of elementary fields are considered.

Finite potential wells

In Sec. 3.4 we have considered what is perhaps the simplest example of quantum dynamics, that is a free particle moving in a box with infinite potential walls. Consider the motion of, say, a one-dimensional particle in a rectangular potential well with finite steps. In Fig. 4.1 we show two of such potentials, symmetric in (a) and asymmetric in (b).

Let us consider the case pictured in Fig. 4.1(a) and indicate with V0 the energy of the potential well. We may therefore distinguish three regions on the x-axis: region I (x < 0), where the potential energy is equal to V0; region II (0 ≤ x ≤ a), where the particle is free; and region III (x > a), where the potential energy is again equal to V0.

In this chapter we shall deal with the most recent and challenging development of quantum theory, and also one of the most important ones for interpretational, foundational, and even technological issues. This field finds its roots in the observation that quantum states can be viewed as bricks of information in a way that is intrinsically different from classical information. As a consequence, the ability to manipulate quantum states translates immediately into a new form of information processing and exchange. What has been discovered during this conceptual passage is that this type of information processing is in many respects much richer than its classical analogue. This has contributed to the understanding of quantum states as an extension of the classical concept of state and not as a defective reality (see also Subsec. 2.3.4 and Sec. 15.5). The impossibility of knowing the value of all observables at the same time that had been seen as a strong limitation in the early days of quantum mechanics, now turns out to be a manifestation of a different – but not necessarily poorer – resource. On the contrary, we have increasingly discovered that superposition and entanglement are additional informational resources. These resources, for instance, allow for certain particular computations that are much faster on a quantum device than on its classical counterpart, and therefore the former is able to solve problems that cannot be practically solved using classical means.

In this chapter we shall deal with the quantum dynamics of an open system. By open quantum system we mean here a system which interacts with an environment (see Sec. 9.4): since we are not interested in the dynamics of the environment, we shall have to describe the evolution of the system in some “effective” way. In particular, if we consider only the evolution of the system, it will be non-unitary, and this will represent the subject of this chapter. As we know, Hamiltonian quantum dynamics is unitary and changes pure states into pure states. On the other hand, non-unitary dynamics changes an initially pure state into a mixture, which must be described by a density matrix (see Ch. 5). In the case of macroscopic systems, the coupling with the environment may be arbitrarily reduced and therefore its influence can be made correspondingly small (see Sec. 1.1). Microscopic systems, however, always couple to the environment and this coupling cannot be considered negligible. This is the reason why the quantum theory of open systems is one of the most important and fundamental chapters of quantum mechanics that, though born in quantum optics, has many implications in almost all fields of physics. The present chapter can be seen as a further development of the measurement theory (see Ch. 9), as open systems manifest a decoherent dynamics (see in particular Sec. 9.4).

In most textbooks, measurement does not receive the full attention it deserves and sometimes is even not treated at all, apart a brief and cryptic mention of the “reduction of the wave packet.” However, in the last decades, the situation has profoundly changed and it is time to consider measurement a fundamental part of quantum mechanics, even, to a certain extent, an important generalization of the traditional theory (see also Chs. 14–15).

This chapter consists of three major parts. In the first block (Secs. 9.1–9.4) we develop the main physical features of the measurement process: the heart of the argument is here represented by the aspects related to the interpretation. In the second part (Secs. 9.5–9.8) we discuss several special (and partly interdependent) topics of measurement: the heart here is represented by experimental aspects. In the third part (Secs. 9.9–9.12) we deal with the measurement process on a more formal plane, making use, in particular, of the generalization represented by the concepts of effect and positive operator valued measure (POVM).

As we have said, the measurement problem is one of the most fundamental issues in the conceptual structure of quantum mechanics (as described in Sec. 9.1) and has a long history that will be examined in Sec. 9.2. In this context, the existence of apparently paradoxical quantum states comes about: the so-called Schrödinger cat states (see Sec. 9.3).

The behavior of light and its interaction with matter is certainly one of the most interesting phenomena of physics. It has puzzled thinkers and scientists in ancient Greece (Archimedes) and through the Middle Ages, at least since the times of Robert Grosseteste (1168–1235), right up to the theories of Galileo Galilei and Isaac Newton. The classical electromagnetic theory of light (see Tab. 13.1) was beautifully established in the second half of the nineteenth century with the Maxwell equations. Quantum optics is nothing other than the quantum theory of light. It finds its roots in Planck's discovery (1900) that the assumption of energy quantization for a harmonic oscillator allowed us to solve the black-body problem (see Subsec. 1.5.1). The successive early steps that led to the quantization of the electromagnetic field include Einstein's explanation of the photoelectric effect with the introduction of the quantum of light (see Subsec. 1.2.1) and the interpretation of atomic spectra (see Subsec. 1.5.4).

Quantum optics is usually not covered by conventional textbooks on quantum mechanics. We include its discussion here for two main reasons: first, because it is a fundamental and advanced application of the basic framework of quantum mechanics, and, second, because in the last 30 years quantum optics has played (and is still playing) a major role in the advancement and understanding of quantum mechanics.

In the first two chapters we have examined the basic principles – superposition (p. 18), complementarity (p. 19), quantization (p. 44), statistical algorithm (p. 57), and correspondence (p. 72) (see also Subsec. 2.3.4) – and the basic entities, observables and states, of quantum mechanics, as well as the main differences with respect to classical mechanics. While what we have discussed so far is rather a static picture of observables and states, in this chapter we shall deal with quantum dynamics, i.e. with the time evolution of quantum-mechanical systems.

Historically, after Bohr had provided a quantized description of the atom (see Subsec. 1.5.4), Einstein showed the quantized nature of photons (see Subsec. 1.2.1), and de Broglie hypothized the wave-like nature of matter (see Subsec. 1.5.5), the first building block of quantum mechanics was provided by the commutation relations, proposed by Heisenberg in 1925, whose consequence is represented by the uncertainty relation (see Subsec. 2.2.7 and Sec. 2.3). This was the subject of the previous chapters. The dynamical part of the theory was proposed by Schrödinger in 1926, and is known as the Schrödinger equation. It is also known as wave mechanics (see Subsec. 1.5.7). In this chapter we shall show that Heisenberg's and Schrödinger's formulations are only two different aspects of the same theory. We shall also come back to this point in Sec. 8.1.1. Here, first we shall derive the fundamental equation which rules quantum dynamics (Sec. 3.1), and, in Sec. 3.2, we shall summarize the main properties of the Schrödinger equation.

Why yet another book on quantum mechanics? Quantum mechanics was born in the first quarter of the twentieth century and has received an enormous number of theoretical and experimental confirmations over the years. It is considered to be the fundamental physical paradigm, and has a wide range of applications, from cosmology to chemistry, and from biology to information sciences. It is one of the greatest intellectual achievements of the past century. As an effect of its invention, the very concept of physical reality was changed, and “observation,” “measurement,” “prediction,” and “state of the system” acquired a new and deeper meaning.

Probability was not unknown in physics: it was introduced by Boltzmann in order to control the behavior of a system with a very large number of particles. It was the missing concept in order to understand the thermodynamics of macroscopic bodies, but the structure of the physical laws remained still deterministic. The introduction of probability was needed as a consequence of our lack of knowledge of the initial conditions of the system and of our inability to solve an enormous number of coupled non-linear differential equations.

In quantum mechanics, the tune is different: if we have 106 radioactive atoms no intrinsic unknown variables decide which of them will decay first. What we observe experimentally seems to be an irreducible random process. The original explanation of this phenomenon in quantum mechanics was rather unexpected.