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The present investigation had its origin in an attempt to explain more fully some interesting phenomena described by Scott Russell and Thomson, and figured by the former. When a small obstacle, such as a fishing line, is moved forward slowly through still water, or (which of course comes to the same thing) is held stationary in moving water, the surface is covered with a beautiful wave-pattern, fixed relatively to the obstacle. On the up-stream side the wave-length is short, and, as Thomson has shown, the force governing the vibrations is principally cohesion. On the down-stream side the waves are longer, and are governed principally by gravity. Both sets of waves move with the same velocity relatively to the water; namely, that required in order that they may maintain a fixed position relatively to the obstacle. The same condition governs the velocity, and therefore the wave-length, of those parts of the wave-pattern where the fronts are oblique to the direction of motion. If the angle between this direction and the normal to the wave-front be called θ, the velocity of propagation of the waves must be equal to v0 cos θ, where v0 represents the velocity of the water relatively to the (fixed) obstacle.
Thomson has shown that, whatever the wave-length may be, the velocity of propagation of waves on the surface of water cannot be less than about 23 centims. per second.
If a glass plate, held horizontally and made to vibrate as for the production of Chladni's figures, be covered with a thin layer of water or other mobile liquid, the phenomena in question may be readily observed. Over those parts of the plate which vibrate sensibly the surface of the liquid is ruffled by minute waves, the degree of fineness increasing with the frequency of vibration. Similar crispations are observed on the surface of liquid in a large wine-glass or finger-glass which is caused to vibrate in the usual manner by carrying the moistened finger round the circumference. All that is essential to the production of crispations is that a body of liquid with a free surface be constrained to execute a vertical vibration. It is indifferent whether the origin of the motion be at the bottom, as in the first case, or, as in the second, be due to the alternate advance and retreat of a lateral boundary, to accommodate itself to which the neighbouring surface must rise and fall.
More than fifty years ago the nature of these vibrations was examined by Faraday with great ingenuity and success. His results are recorded in an Appendix to a paper on a Peculiar Class of Acoustical Figures, headed “On the Forms and States assumed by Fluids in Contact with Vibrating Elastic Surfaces.” In more recent times Dr L. Matthiessen has travelled over the same ground, and on one very important point has recorded an opinion in opposition to that of Faraday.
In the Philosophical Magazine for June 1877 [Art. 46, vol. I. p. 320] I described some observations which proved that the note of an open organpipe, when blown in the normal manner, was higher in pitch than the natural note of the pipe considered as a resonator. The note of maximum resonance was determined by putting the ear into communication with the interior of the pipe, and estimating the intensity of sounds of varying pitch produced externally.
A more accurate result may be obtained with the method used by Blaikley, in which the external sound remains constant and the adjustment is effected by tuning the resonator to it. About two inches were cut off from the upper end of a two-foot metal organ-pipe, and replaced by an adjustable paper slider. At a moderate distance from the lower end of the pipe a tuning-fork was mounted, and was maintained in regular vibration by the attraction of an electromagnet situated on the further side, into which intermittent currents from an interrupter were passed. Neither the fork nor the magnet were near enough to the end of the pipe to produce any sensible obstruction. By comparison with a standard, the pitch of the fork thus vibrating was found to be 255 of König's scale. The resonance of the pipe was observed from a position not far from the upper end, where but little of the sound of the fork could be heard independently; and the paper slider was adjusted to the position of maximum effect.
In his inaugural address to the Society of Telegraph Engineers, and in a subsequent communication to the Royal Society, Prof. Hughes has described a series of interesting experiments, which have attracted a good deal of attention in consequence both of the official position and known experimental skill of the author. Some of the conclusions which he advances can hardly be sustained, and have met with severe criticism at the hands of Weber, Heaviside, and others. There are certain other points raised by him, or suggested by his work, which seem worthy of consideration; and I propose in the present paper to give an account of some investigations, mainly experimental, carried on during the summer months, which may, I hope, tend to settle some controverted questions.
Prof. Hughes's first apparatus consists of a Wheatstone's quadrilateral, with a telephone in the bridge, one of the sides of the quadrilateral being the wire or coil under examination, and the other three being the parts into which a single German-silver wire is divided by two sliding contacts. If the battery-branch be closed, and a suitable interrupter be introduced into the telephone-branch, balance may be obtained by shifting the contacts. Provided that the interrupter introduces no electromotive force of its own, the balance indicates the proportionality of the four resistances.
Experimenters in Acoustics have discovered more than one set of phenomena, apparently depending for their explanation upon the existence of regular currents of air resulting from vibratory motion, of which theory has as yet rendered no account. This is not, perhaps, a matter for surprise, when we consider that such currents, involving as they do circulation of the fluid, could not arise in the absence of friction, however great the extent of vibration. And even when we are prepared to include in our investigations the influence of friction, by which the motion of fluid in the neighbourhood of solid bodies may be greatly modified, we have no chance of reaching an explanation, if, as is usual, we limit ourselves to the supposition of infinitely small motion and neglect the squares and higher powers of the mathematical symbols by which it is expressed.
In the present paper three problems of this kind are considered, two of which are illustrative of phenomena observed by Faraday. In these problems the fluid may be treated as incompressible. The more important of them relates to the currents generated over a vibrating plate, arranged as in Chladni's experiments. It was discovered by Savart that very fine powder does not collect itself at the nodal lines, as does sand in the production of Chladni's figures, but gathers itself into a cloud which, after hovering for a time, settles itself over the places of maximum vibration.
The very beautiful experiment in question, described by C. Christiansen in Wiedemann's Annalen for November 1884, consists in immersing glass-power in a mixture of benzole and bisulphide of carbon of such proportions that for one part of the spectrum the indices of the solid and of the fluid are the same. Being interested in this subject from having employed the same principle for a direct-vision spectroscope (Phil. Mag. January 1880, p. 53) [vol. I. p. 456], I have repeated Christiansen's experiment in a somewhat improved form, which it may be worth while briefly to describe, as the matter is one of great optical interest.
I must premise that the beauty of the effect depends upon the correspondence of index being limited to one part of the spectrum. Rays lying within a very narrow range of refrangibility traverse the mixture freely, but the neighbouring rays are scattered laterally, much as in passing ground glass. Two complementary colours are therefore exhibited, one by direct, and the other by oblique, light. In order to see these to advantage, there should not be much diffused illumination; otherwise the directly transmitted monochromatic light is liable to be greatly diluted. The prettiest colours are obtained when the undisturbed rays are from the green; but the greatest general transparency corresponds to a lower point in the spectrum.
In the hope of finding a clue as to the origin of some of the minor anomalies of Clark's cells, I have made experiments upon the e.m.f. of combinations, in which two different strengths of zinc amalgam take the place of the zinc and pure mercury of the Clark cell. No mercurous sulphate is employed, the liquid being simply a saturated solution of zinc sulphate.
If the same kind of amalgam be used for both poles, the symmetry is complete, and there should be no e.m.f. But if we take for one pole a strong, but fluid, amalgam, and for the other the same amalgam diluted with an equal volume of pure mercury, we find a very sensible e.m.f., the strong amalgam corresponding to the zinc of the ordinary Clark. In my experiment the e.m.f. was ·004 Clark, and remained pretty constant from day to day. In another cell the same strong amalgam was used for one pole, and for the other pole was diluted with three times its volume of pure mercury. In this case the e.m.f. was ·009 Clark.
If we replace the diluted amalgam with pure mercury, we obtain (without mercurous sulphate) nearly the full e.m.f. of the Clark cell, but, as might be expected, the force is very unsteady. From this it would seem that the function of the mercurous sulphate in the usual form of cell is to retain the purity of the mercury, and that the e.m.f. is largely due to the affinity of mercury for zinc.
In Acoustics we have sometimes to consider the incidence of aerial waves upon porous bodies, in whose interstices some sort of aerial continuity is preserved. Tyndall has shown that in many cases sound penetrates such bodies, e.g. thick pieces of felt, more freely than would have been expected, though it is reflected from quite thin layers of continuous solid matter. On the other hand, a hay-stack seems to form a very perfect obstacle. It is probable that porous walls give a diminished reflection, so that within a building so bounded resonance is less prolonged than would otherwise be the case.
When we inquire into the matter mechanically, it is evident that sound is not destroyed by obstacles as such. In the absence of dissipative forces, what is not transmitted must be reflected. Destruction depends upon viscosity and upon conduction of heat; but the influence of these is enormously augmented by the contact of solid matter exposing a large surface. At such a surface the tangential as well as the normal motion is hindered, and a passage of heat to and fro takes place, as the neighbouring air is heated and cooled during its condensations and rarefactions. With such rapidity of alternations as we are concerned with in the case of audible sounds, these influences extend to only a very thin layer of the air and of the solid, and are thus greatly favoured by attenuation of the masses.
In a Lecture delivered by Mr Willoughby Smith before the Royal Institution in June last (see Proceedings) some experiments are detailed, which are considered to afford an explanation of discrepancies in the results of various investigators relating to the ohm, or absolute unit of electrical resistance. As having given more attention than probably anyone else in recent years to this subject, I should like to make a few remarks upon Mr Willoughby Smith's views, which naturally carry weight corresponding to the good service done by the author in this branch of science.
In the first series of experiments a primary circuit is arranged in connection with a battery and interrupter, and a secondary circuit in connection with a galvanometer and commutator of such a character that the make and break induced currents pass in the same direction through the instrument. Under these circumstances it is found that at high speeds the insertion of a copper plate between the primary and secondary spirals entails a notable diminution in the galvanometer deflection, and this result is regarded as an indication that the molecules of copper need to be polarised by the lines of force—an operation for which there is not time at the higher speeds. The orthodox explanation of the experiment would be that currents are developed by induction in the copper sheet, which thus screens the secondary spiral from the action of the primary, and the result is exactly what might have been anticipated from known electrical principles.
At the present time, and in view of the projected conference at Paris, the subject of the present paper is engaging a large share of attention; and Prof. G. Wiedemann has published an interesting discussion of some of the methods that have been employed. I have thought it might be of service if I also were to place upon record the views that I have been led to entertain, and which are the result of a good deal of experience.
Resistance being of the dimensions of velocity, its absolute measurement involves the absolute measurement of a length and of a time. The latter is usually the time of a vibration of a suspended magnet, and it can be determined without much difficulty. In the b.a. method it is the time of rotation of the revolving coil, and it can be obtained with all desirable accuracy. In this respect there is not much to choose between one method and another; but when we come to consider the manner in which the linear measurement enters, important differences reveal themselves. These will be discussed in detail presently; but for the moment it will be sufficient to say that the presumption is in favour of any method which requires only a single linear measurement. It is true that this question cannot be decided without regard to the subject of the measurement; but, with scarcely an exception, it is necessary to know the mean radius of a coil of several layers of insulated wire.
It is little to the credit of English science that the fundamental optical theorems of Cotes and Smith should have passed almost into oblivion, until rediscovered in a somewhat different form by Lagrange, Kirchhoff, and von Helmholtz. Even now the general law governing apparent brightness seems to be very little understood, although it has acquired additional importance in connection with the theory of exchanges and the second law of Thermodynamics. In seeking the most natural basis for the law of magnifying, usually attributed to Lagrange, I was struck with the utility of Smith's phrase “apparent distance,” which has never been quite forgotten, and was thus induced to read his ch. v. book ii., founded upon Cotes's “noble and beautiful theorem.” I think that it may be of service to present a re-statement, as nearly as may be in his own words, of the more important of the laws deduced by Smith, accompanied by some remarks upon the subject regarded from a more modern point of view.
The general problem is thus stated:—
“To determine the apparent distance, magnitude, situation, degree of distinctness and brightness, the greatest angle of vision and visible area, of an object seen by rays successively reflected from any number of plane or spherical surfaces, or successively refracted through any number of lenses of any sort, or through any number of different mediums whose surfaces are plane or spherical. With an application to Telescopes and Microscopes.”
The author called attention to the difficulty of reconciling the values of Regnault and Hagen with the phenomena observed by Crookes relating to the viscosity of gases at high exhaustions. The total gaseous pressure in the working chamber cannot be less than that of the mercury at the pump. If the penetration of mercury vapour be prevented by chemical means, some other gas must be present in equivalent quantity. If the value of Regnault and Hagen is substantially correct, it does not appear how the phenomena [of viscosity] could vary so much as they are observed to do at the highest degrees of exhaustion as measured by the McLeod gauge. The question then arises whether the value of mercury tension hitherto received may not be much in excess of the truth. In Hagen's researches it is assumed without reason that the pressure in a chamber of variable temperature is governed by the temperature of the coldest part, but this consideration tells in the wrong direction. It was suggested that possibly a change in the capillary constant, or currents in the fluid mercury at the chilled surface of the meniscus, might have had something to do with the minute changes of level which have been attributed to differences of pressure in the mercury vapour.
The experiments herein described were made in the spring and summer of 1880, with the assistance of Mrs Sidgwick. Section 2 was indeed written out as it now stands in August of that year. There were some other points which I had hoped to submit to examination, but hitherto opportunity has not been found.
On some of the Circumstances which, influence the Scattering of a nearly Vertical Jet of Liquid
1. It has been already shown [Art. 59, vol. I. p. 372] that the normal scattering of a nearly vertical jet is due to the rebound of the drops when they come into collision. If, by any means, the drops can be caused to amalgamate at collision, the appearance of the jet is completely transformed. This result occurs if a feebly electrified body be held near the place of resolution into drops, and it was also observed to follow the addition of a small quantity of soap to the water of which the jet was composed. In trying to repeat the latter experiment in May, 1880, at Cambridge, I was astonished to find that even large additions of soap failed to prevent the scattering. Thinking that the difference might be connected with the hardness of the Cambridge water—at home I had used rain water—I repeated the observations with distilled water, but without finding any explanation. The jet of distilled water scattered freely, both with and without soap, and could only be prevented from doing so by electricity. Eventually the anomalies were traced to differences in the character of the soap.
The subject of this excellent little book includes the Mechanical Properties of matter, and much that is usually treated under the head of Chemical Physics, such as Diffusion and Capillarity. It might be difficult to give a reason why electric and thermal conductivities of mercury, for example, should not be included among its properties as much as its density and its capillarity; but the distinction is convenient, and to some extent sanctioned by usage.
In the introductory chapters the author expounds some rather peculiar views with perhaps more insistence than is desirable in an elementary work. The word “force” is introduced apologetically, and with the explanation that, “as it does not denote either matter or energy, it is not a term for anything objective.” No one will dispute the immense importance of the property of conservation, but the author appears to me to press his view too far. As Dr Lodge has already pointed out, if conservation is to be the test of existence, Prof. Tait himself does not exist. I forbear from speculating what Dr Lodge will say when he reads on p. 11 that “not to have its price is conclusive against objectivity.”
Chapters IV. to VII. form an elementary treatise on Mechanics in which even the learned reader will find much that is interesting in the way of acute remark and illustration.
The purpose of this instrument is to exhibit external objects as they would be seen either with the naked eye, or through a telescope, if lighted with approximately monochromatic light; that is, to do more perfectly what is done roughly by a coloured glass.
The arrangement is not new, though I am not aware that it has ever been described. In 1870 I employed it for determinations of absorption, and, if my memory serves me right, I heard soon afterwards from Clerk-Maxwell that he also had used it. It is, indeed, a very slight modification of Maxwell's colour-box.
In the ordinary form of that instrument, white light admitted through a slit is rendered parallel by a collimating lens, dispersed by flint-glass prisms, and then brought to a focus at a screen, upon which accordingly a pure spectrum is formed. This screen is perforated by a second slit, immediately behind which the observer places his eye. It is evident that the light passing the aperture is approximately monochromatic, so that the observer, if he focuses his eye suitably, will see the prism illuminated with this kind of light. The only addition now required to convert the instrument into a monochromatic telescope is a lens placed just within the first slit, of such power as to throw an image of external objects upon the prism or diaphragm upon which the eye is focused.