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An able discussion of the principal determinations of the above quantity, usually denoted by ν, has been given in the Reports of the Paris Physical Congress (1900) by H. Abraham—himself a contributor to the series. This ground it is unnecessary to retraverse, but I desire to place on record one or two suggestions which have occurred to me but which I may probably have no opportunity of myself putting into practice.
The most approved methods involve the construction either of a condenser or of an electrometer, of which in the first case the capacity, and in the second the potential, can be calculated in electrostatic measure. The first method, on the whole, offers the greatest advantages, and I preferred it when (about 1882, and with the advice of Prof. Stuart) the Cambridge condenser was designed. In this method two currents are compared by a galvanometer. The first is that due to a given electromotive force in a resistance whose value is known in electromagnetic measure. The second is the intermittent current due to the same electromotive force charging n times per second a condenser whose capacity is known from the data of construction in electrostatic measure. The comparison may be conducted by the aid of Wheatstone's bridge.
There are, however, one or two matters as to which doubts may arise. Thus it is essential that the commutator by whose action the condenser is periodically charged and discharged, should introduce no electromotive force on its own account.
The importance of the consequences deduced by Boltzmann and W. Wien from the doctrine of the pressure of radiation has naturally drawn increased attention to this subject. That æthereal vibrations must exercise a pressure upon a perfectly conducting, and therefore perfectly reflecting, boundary was Maxwell's deduction from his general equations of the electromagnetic field; and the existence of the pressure of light has lately been confirmed experimentally by Lebedew. It seemed to me that it would be of interest to inquire whether other kinds of vibration exercise a pressure, and if possible to frame a general theory of the action.
We are at once confronted with a difference between the conditions to be dealt with in the case of æthereal vibrations and, for example, the vibrations of air. When a plate of polished silver advances against waves of light, the waves indeed are reflected, but the medium itself must be supposed capable of penetrating the plate; whereas in the corresponding case of aerial vibrations the air as well as the vibrations are compressed by the advancing wall. In other cases, however, a closer parallelism may be established. Thus the transverse vibrations of a stretched string, or wire, may be supposed to be limited by a small ring constrained to remain upon the equilibrium line of the string, but capable of sliding freely upon it.
The presence of helium in the residue after removal of nitrogen from this gas was proved in a former paper, but there was some doubt as to the relative proportions of argon and helium. A fresh sample, kindly collected by Dr Richardson, has therefore been examined. Of this 2,500 c.c., submitted to electric sparks in presence of oxygen, gave a final residue of 37 c.c., after removal of all gases known until recently. The spectrum of the residue, observed at atmospheric pressure, showed argon, and the D3 line of helium very plainly.
The easy visibility of D3 suggested the presence of helium in some such proportion as 10 per cent., and this conjecture has been confirmed by a determination of the refractivity of the mixture. It may be remembered that while the refractivity of argon approaches closely that of air, the relative number being 0·961, the refractivity of helium (as supplied to me by Professor Ramsay) is very low, being only 0·146 on the same scale. If we assume that any sample of gas is a mixture of these two, its refractivity will determine the proportions in which the components are present.
The observations were made by an apparatus similar in character to that already described, but designed to work with smaller quantities of gas.
On a recent occasion I remarked that Stewart's work appeared to me to be insufficiently recognized upon the Continent. One reason for this is probably the comparative inaccessibility of the Edinburgh Transactions in which his first paper appeared. Another may be found in the fact that the paper itself is not well arranged, and that the principal conclusion is put forward in the first instance as if it were the result of Stewart's special experiments. The experiments were indeed of great value; but this course gave an opening to Kirchhoff's objection that “this proof [of the law that the absorption of a plate equals its radiation and that for every description of heat] cannot be a strict one, because experiments which have only taught us concerning more and less, cannot strictly teach us concerning equality.” I am inclined to think that Stewart would have received more recognition if he had never experimented at all!
While yielding to no one in admiration for Kirchhoff, I can hardly regard him as in this matter an impartial critic. In a paper which should be studied by the historical inquirer, Stewart himself protests against some of Kirchhoff's remarks, and to my judgment makes out his case. In his excellent Handbuch der Spectroscopie, recently published, Prof. Kayser, with evident desire to be impartial, gives Stewart much, but not all, of the credit that I would claim for him.
As some recent viva voce remarks of mine have received an interpretation more wide than I intended, I shall be glad to be allowed to explain that when (now several years ago) I became acquainted with the work of van t' Hoff I was soon convinced of the great importance of the advances due to him and his followers. The subject has been prejudiced by a good deal of careless phraseology, and this is probably the reason why some distinguished physicists and chemists have refused their adhesion. It must be admitted, further, that the arguments of van t' Hoff are often insufficiently set out, and are accordingly difficult to follow. Perhaps this remark applies especially to his treatment of the central theorem, viz. the identification of the osmotic pressure of a dissolved gas with the pressure which would be exercised by the gas alone if it occupied the same total volume in the absence of the solvent. From this follows the formal extension of Avogadro's law to the osmotic pressure of dissolved gases, and thence by a natural hypothesis to the osmotic pressure of other dissolved substances, even although they may not be capable of existing in the gaseous condition. If I suggest a somewhat modified treatment, it is not that I see any unsoundness in van t' Hoff's argument, but because of the importance of regarding a matter of this kind from various points of view.
In a paper published sixteen years ago I drew attention to a peculiarity of the magnetic rotation of the plane of polarisation arising from the circumstance that the rotation is in the same absolute direction whichever way the light may be travelling. “A consequence remarkable from the theoretical point of view is the possibility of an arrangement by which the otherwise general optical law of reciprocity shall be violated. Consider, for example, a column of diamagnetic medium exposed to such a force that the rotation is 45°, and situated between two Nicols whose principal planes are inclined to one another at 45°. Under these circumstances light passing one way is completely stopped by the second Nicol, but light passing the other way is completely transmitted. A source of light at one point A would thus be visible at a second point B, when a source at B would be invisible at A; a state of things at first sight inconsistent with the second law of thermodynamics.” (Phil. Trans. CLXXVI. p. 343, 1885; Scientific Papers, Vol. II. p. 360.) It is here implied that the inconsistency is apparent only, but I did not discuss it further.
In his excellent report (“Les Lois théoriques du Rayonnement, Rapports présentés au Congrès International de Physique,” Paris, 1900, Vol. II. p. 29), W. Wien, considering the same experimental combination of Nicols and magnetised dielectric, arrives at a contrary conclusion. It may be well to quote his statement of the case.
The subject under discussion includes both natural and artificial flight. Although we are familiar with the flight of birds, there are many interesting questions which arise in connexion with natural flight, and some of them are yet very obscure.
In still air a bird, being heavier than the fluid displaced, cannot maintain his level for more than a short time without working his wings. In this matter the vicarious principle holds good. If the bird is not to fall, something must fall instead of him, and this can only be air. The maintenance of the bird thus implies the perpetual formation of a downward current of air, and involves therefore performance of work. Later we shall consider more particularly how this work is applied; but a preliminary difficulty remains to be discussed. It is well known that large birds, such as vultures and pelicans, are often observed to maintain their level for considerable periods of time, without flapping or visibly working their wings. On a smaller scale, and in more special situations, sea-gulls in these latitudes perform similar feats. This question of the soaring or sailing flight of birds has given rise to much difference of opinion. Few of the naturalists, to whom we owe the observations, are familiar with mechanical principles, and thus statements are often put forward which amount to mechanical impossibilities.
Careful experiments by Heydweiller, published in the last number of Drude's Annalen (Vol. v. p. 394), lead their author to the conclusion that in certain cases chemical action is accompanied by a minute, but real, alteration of weight. The chemical actions here involved must be regarded as very mild ones, e.g. the mere dissolution of cupric sulphate in water, or the substitution of iron for copper in that salt.
The evidence for the reality of these changes, which amount to 0·2 or 0·3 mg., and are accordingly well within the powers of a good balance to demonstrate, will need careful scrutiny; but it may not be premature to consider what is involved in the acceptance of it. The first question which arises is—does the mass change as well as the weight? The affirmative answer, although perhaps not absolutely inconsistent with any well ascertained fact, will certainly be admitted with reluctance. The alternative—that mass and weight are not always in proportion—involves the conclusion, in contradiction to Newton, that the length of the seconds' pendulum at a given place depends upon the material of which the bob is composed. Newton's experiment was repeated by Bessel, who tried a number of metals, including gold, silver, lead, iron, zinc, as well as marble and quartz, and whose conclusion was that the length of the seconds' pendulum formed of these materials did not vary by one part in 60,000.
The phenomena of light and colour exhibited in the polariscope when strained glass is interposed between crossed nicols are well known to every student of optics. The strain may be of a permanent character, as in glass imperfectly annealed or specially unannealed, or it may be temporary, due to variations of temperature or to mechanical force applied from without. One of the best examples under the last head is that of a rectangular bar subjected to flexure, the plane of the flexure being perpendicular to the course of the light. The full effect is obtained when the length of the bar is at 45° to the direction of polarization. The revival of light is a maximum at the edges, where the material traversed is most stretched or compressed, while down the middle a dark bar is seen representing the “neutral axis.” It is especially to be noted that the effect is due to the glass being unequally stretched in the two directions perpendicular to the line of vision. Thus in the case under discussion no force is operative perpendicular to the length of the bar. Under a purely hydrostatic pressure the singly refracting character of the material would not be disturbed.
It is fitting that the present season should not pass without a reference on these evenings to the work of him whose tragic death a few months since was felt as a personal grief and loss by every member of the Royal Institution. With much diffidence I have undertaken the task to-night, wishing that it had fallen to one better qualified by long and intimate acquaintance to do justice to the theme. For Tyndall was a personality of exceeding interest. He exercised an often magical charm upon those with whom he was closely associated, but when his opposition was aroused he showed himself a keen controversialist. My subject of to-night is but half the story.
Even the strictest devotion of the time at my disposal to survey of the scientific work of Tyndall will not allow of more than a very imperfect and fragmentary treatment. During his thirty years of labour within these walls he ranged over a vast field, and accumulated results of a very varied character, important not only to the cultivators of the physical sciences, but also to the biologist. All that I can hope to do is to bring back to your recollection the more salient points of his work, and to illustrate them where possible by experiments of his own devising.