To save content items to your account,
please confirm that you agree to abide by our usage policies.
If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account.
Find out more about saving content to .
To save content items to your Kindle, first ensure no-reply@cambridge.org
is added to your Approved Personal Document E-mail List under your Personal Document Settings
on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part
of your Kindle email address below.
Find out more about saving to your Kindle.
Note you can select to save to either the @free.kindle.com or @kindle.com variations.
‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi.
‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.
Superconductivity is a quantum state of matter that occurs through a phase transition driven by thermal fluctuations. In this state, materials show ideal electric conductivity and ideal diamagnetism to a very good approximation. Two main classes of superconductors, type I and type II, can be distinguished with regards to flux penetration under an applied magnetic field. The properties of these two types are first discussed in detail. Next, the Ginzburg–Landau theory is developed and it is shown that in the presence of a magnetic field, when the ratio of penetration and coherence lengths is smaller than 1⁄√2 the superconductor behaves as type I, while it behaves as type II when this ratio is larger than 1⁄√2. In this second case, the flux penetrates through vortices that form a hexagonal lattice. Finally, in the last part, the microscopic BCS theory is discussed in order to provide an understanding of the physical origin of superconductivity.
The chapter is an introduction to basic equilibrium aspects of phase transitions. It starts by reviewing thermodynamics and the thermodynamic description of phase transitions. Next, lattice models, such as the paradigmatic Ising model, are introduced as simple physical models that permit a mechano-statistical study of phase transitions from a more microscopic point of view. It is shown that the Ising model can quite faithfully describe many different systems after suitable interpretation of the lattice variables. Special emphasis is placed on the mean-field concept and the mean-field approximations. The deformable Ising model is then studied as an example that illustrates the interplay of different degrees of freedom. Subsequently, the Landau theory of phase transitions is introduced for continuous and first-order transitions, as well as critical and tricritical behaviour are analysed. Finally, scaling theories and the notion of universality within the framework of the renormalization group are briefly discussed.
The chapter starts by introducing the basic concepts of metastable and unstable states as well as time scales that control the occurrence of phase transitions. The limits for phase transitions taking place in equilibrium and out-of-equilibrium conditions are then established. In the latter case, thermally activated and athermal limits are distinguished associated with those situations where the transition is either driven or not driven by thermal fluctuations, respectively. Then the formal theory of the decay of metastable and unstable states in systems with conserved and non-conserved order parameters is developed. This general theory is in turn applied to the study of homogeneous and heterogeneous nucleation, spinodal decomposition and late stages of coarsening and domain growth.