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Since the publication of the second part of the first volume, (1810) some important essays on the subject of heat have appeared, which have a direct bearing upon some points of the doctrine on that subject inculcated in the said volume. It may be proper to state the results, with such remarks and reflections as have occurred in the consideration of them.
In the Annales de Chimie for January 1813, also in the Annals of Philosophy, vol. 2, we find a Memoir on the specific heat of different gases, by M. M. De la Roche and Berard. This exhibits a most laborious and refined series of experiments on this most difficult subject. Great merit seems to be due to them, both for invention and execution.
It is unnecessary to describe the particulars of the apparatus and the mode of conducting the experiments, as a description may be found as above referred. It is sufficient to observe that the calorimeter used was a copper cylinder of 3 inches diameter and 6 in length, filled with water, and having a serpentine tube 5 feet in length, running through the interior and opening at both ends on the outside of the vessels. By means of this tube a regular current of any gas of a given temperature (212°) might be passed through the vessel so as to part with its excess of temperature to the water.
The work now submitted to the public was begun to be printed in 1817; and the 13th and 14th sections, containing the oxides and sulphurets, were printed off before the end of October of the same year. The printing of the rest of the work to the appendix was finished in September, 1821. One sheet of the appendix was printed at the end of 1823; but no addition was afterwards made till May, 1826; when the printing was resumed, and has been continued to the present time.
It may be asked, what were the motives for such a plan of procedure. To this it may be replied, that soon after the publication of the first volume (in 1810), I began to prepare materials, and to institute experiments, relating to the oxides, &c, with occasional diversions into other departments of chemistry, as circumstances arose. As a great portion of my time was always necessarily engaged in professional duties, and as that part of the work I was about to commence was one running into detail, I thought it would be best to print it as I proceeded, whilst the train of thought and of experiments was fresh in view. The advantage in this case was expected to be partly at least counterbalanced by the loss of discoveries and improvements likely to be made in the interval between the printing and publishing of the several articles.