Published online by Cambridge University Press: 31 October 2025
This chapter discusses light–matter interactions from a semiclassical point of view. By expanding the electromagnetic field into a Taylor series we derive the multipolar interaction potential and particle-field Hamiltonian. Then, using the Green function formalism, we calculate the fields of an oscillating dipole and, based on Poynting’s theorem, derive a general expression for the rate of energy dissipation in an arbitrary environment. This expression leads to the concept of local density of states (LDOS) and provides a direct link to spontaneous emission and atomic decay rates. The rate of energy dissipation of an oscillating dipole is also used to derive the absorption cross-section in terms of the polarizability. By accounting for radiation reaction and scattering losses, we obtain a compact expression for the dynamic polarizability. Dipole radiation and atomic decay rates can be enhanced via LDOS engineering, and the enhancement factor is referred to as the Purcell factor. We show that if the LDOS gets enhanced in a certain frequency range, it must be reduced in other frequency ranges, a feature described by the LDOS sum rule. After discussing the properties of a single dipole, we continue with analyzing the interaction between multiple dipoles. We derive the interaction potential and calculate the energy transfer rate between dipoles. For short distances we recover the famous Förster energy transfer formula. If the interaction energy becomes sufficiently large, we enter the regime of strong coupling, which gives rise to hybridized and delocalized modes, level splittings, and entanglement.
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