Published online by Cambridge University Press: 07 September 2010
My dear Lockyer,—You might perhaps like that I should put on paper the substance of the remarks I made last night as to the evidence of the dissociation of calcium.
When a solid body such as a platinum wire, traversed by a voltaic current, is heated to incandescence, we know that as the temperature increases, not only does the radiation of each particular refrangibility absolutely increase, but the proportion of the radiations of the different refrangibilities is changed, the proportion of the higher to the lower increasing with the temperature. It would be in accordance with analogy to suppose that as a rule the same would take place in an incandescent surface, though in this case the spectrum would be discontinuous instead of continuous. Thus if A, B, C, D, E denote conspicuous bright lines, of increasing refrangibility, in the spectrum of the vapour, it might very well be that at a comparatively low temperature A should be the brightest and the most persistent; at a higher temperature, while all were brighter than before, the relative brightness might be changed, and C might be the brightest and the most persistent, and at a still higher temperature E. If, now, the quantity of persistence were in each case reduced till all lines but one disappeared, the outstanding line might be A at the lowest temperature, C at the higher, E at the highest.
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