Published online by Cambridge University Press: 31 October 2009
Crystals are solid materials having regular atomic arrangements characterized by periodicity and anisotropy. These properties are universally present, irrespective of whether the crystal is inorganic or organic, in living systems or in the inanimate world. Crystals exhibit various external forms, as represented by the elaborately varied dendritic forms of snow crystals or the hexagonal prismatic forms of rock-crystal. This variety of shape has stimulated scientific curiosity since the seventeenth century, since when intensive efforts have been made to understand the reasons why and how crystals can take a variety of forms.
The forms that crystals take result from the way in which crystals grow. The mechanism of growth is recorded in various forms in each individual crystal, regardless of size. The same crystal species may show different crystal forms (for example, polyhedral, skeletal, and dendritic), depending on growth conditions. Spiral growth step patterns, which record the growth process at the nanometer scale, have been observed on crystal faces. In single crystals, fluctuations in growth rates during the growth process are recorded as variations in perfection and homogeneity, such as growth sectors, growth banding, and three-dimensional distribution of lattice defects such as dislocations. The texture and structure of minute polycrystalline aggregate also record the growth history. These fluctuations are observed not only in crystals formed by inorganic processes, but also in those formed in living organs like bones, teeth or shells, or in calculus formed in various organs through the excretion of unnecessary components.
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