The decomposability number of a von Neumann algebra
\mathcal{M} (denoted by
\text{dec}\left( \mathcal{M} \right)) is the greatest cardinality of a family of pairwise orthogonal non-zero projections in
\mathcal{M}. In this paper, we explore the close connection between
\text{dec}\left( \mathcal{M} \right) and the cardinal level of the Mazur property for the predual
{{\mathcal{M}}_{*}} of
\mathcal{M}, the study of which was initiated by the second author. Here, our main focus is on those von Neumann algebras whose preduals constitute such important Banach algebras on a locally compact group
G as the group algebra
{{L}_{1}}(G), the Fourier algebra
A(G), the measure algebra
M(G), the algebra
LUC{{(G)}^{*}}, etc. We show that for any of these von Neumann algebras, say
\mathcal{M}, the cardinal number dec
(\mathcal{M}) and a certain cardinal level of the Mazur property of
{{\mathcal{M}}_{*}} are completely encoded in the underlying group structure. In fact, they can be expressed precisely by two dual cardinal invariants of
G: the compact covering number
\kappa (G) of
G and the least cardinality
\mathcal{X}(G) of an open basis at the identity of
G. We also present an application of the Mazur property of higher level to the topological centre problem for the Banach algebra
A{{(G)}^{**}}.