In this contribution we present the results from a1 homogeneous quantitative spectroscopic analysis of ∼400 Galactic O-type stars targeted by the IACOB and OWN surveys. The ultimate objective is to perform a modern reassessment of one of the long-standing problems in the field of massive stars: the elusive detection of mid O-type stars close to the “canonical” theoretical ZAMS. We first provide statistically significant evidence of the existence of a clear lack of stars in our sample populating the region of the spectroscopic HR diagram approximately delimited by the theoretical ZAMS, the ∼ 40 and ∼ 70 M⊙ single evolutionary tracks and the 2 Myr isochrone. We then evaluate if this empirical result could be a result of possible limitations of our analysis strategy and/or the existence of potential observational biases affecting the compiled sample. Once both explanations are investigated, we evaluate the possibility that a modification of the efficiency of mass accretion during the star formation process could lead to a new (corrected) theoretical ZAMS in better accordance with our empirical results.

We present the results of binary population simulations of carbon- and nitrogen-enhanced metal-poor (CEMP and NEMP) stars. We show that the observed paucity of very nitrogen-rich stars puts strong constraints on possible modifications of the initial mass function at low metallicity.

A recent reanalysis of the fluorine abundance in three Galactic Asymptotic Giant Branch (AGB) carbon stars (TX Psc, AQ Sgr and R Scl) by Abia et al. (2009) results in estimates of fluorine abundances systematically lower by ∼0.8 dex on average, with respect to the sole previous estimates by Jorissen, Smith & Lambert (1992). The new F abundances are in better agreement with the predictions of full-network stellar models of low-mass (<3 M⊙) AGB stars.