We study a class of simulated annealing type algorithms for global minimization with general acceptance probabilities. This paper presents simple conditions, easy to verify in practice, which ensure the convergence of the algorithm to the global minimum with probability 1.

We consider non-homogeneous Markov chains generated by the simulated annealing algorithm. We classify states according to asymptotic properties of trajectories. We identify recurrent and transient states. The set of recurrent states is partitioned into disjoint classes of asymptotically communicating states. These classes correspond to atoms of the tail sigma-field. The results are valid under the weak reversibility assumption of Hajek.

The paper is concerned with aspects of the behaviour of the products of finite stochastic matrices, the methods used in the proofs being of a probabilistic nature. The main result of the paper (Theorem 1) presents a general picture of the asymptotic behaviour of the transition probabilities between various groups of states. A unified treatment of some results of non-homogeneous Markov chain theory pertaining to weak ergodicity is then given.