Motivated by the recent work of Zhi-Wei Sun [‘Problems and results on determinants involving Legendre symbols’, Preprint, arXiv:2405.03626], we study some matrices concerning subgroups of finite fields. For example, let $q\equiv 3\pmod 4$ be an odd prime power and let $\phi $ be the unique quadratic multiplicative character of the finite field $\mathbb {F}_q$. If the set $\{s_1,\ldots ,s_{(q-1)/2}\}=\{x^2:\ x\in \mathbb {F}_q\setminus \{0\}\}$, then we prove that

$$ \begin{align*}\det[t+\phi(s_i+s_j)+\phi(s_i-s_j)]_{1\le i,j\le (q-1)/2}=\bigg(\frac{q-1}{2}t-1\bigg)q^{{(q-3)}/{4}}.\end{align*} $$

This confirms a conjecture of Zhi-Wei Sun.

Motivated by the work initiated by Chapman [‘Determinants of Legendre symbol matrices’, Acta Arith. 115 (2004), 231–244], we investigate some arithmetical properties of generalised Legendre matrices over finite fields. For example, letting $a_1,\ldots ,a_{(q-1)/2}$ be all the nonzero squares in the finite field $\mathbb {F}_q$ containing q elements with $2\nmid q$, we give the explicit value of the determinant $D_{(q-1)/2}=\det [(a_i+a_j)^{(q-3)/2}]_{1\le i,j\le (q-1)/2}$. In particular, if $q=p$ is a prime greater than $3$, then

$$ \begin{align*}\bigg(\frac{\det D_{(p-1)/2}}{p}\bigg)= \begin{cases} 1 & \mbox{if}\ p\equiv1\pmod4,\\ (-1)^{(h(-p)+1)/2} & \mbox{if}\ p\equiv 3\pmod4\ \text{and}\ p>3, \end{cases}\end{align*} $$

where $(\frac {\cdot }{p})$ is the Legendre symbol and $h(-p)$ is the class number of $\mathbb {Q}(\sqrt {-p})$.