We prove the existence of multiple bound states of the nonlinear Schrödinger equation −Δu + V(x)u = f(u). Here the linear potential V is continuous and bounded from below, and the nonlinearity f is of asymptotically linear type. We show that, under certain assumptions on the spectrum of the Schrödinger operator −Δ + V and the asymptotic behaviour of f(u)/u, the above equation has at least four non-trivial solutions, two of them sign changing.