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Laboratory evidence for the formation of hydrogenated fullerene molecules

Published online by Cambridge University Press:  12 October 2020

J. D. Thrower Open the ORCID record for J. D. Thrower [Opens in a new window] ,
G. Pantazidis Open the ORCID record for G. Pantazidis [Opens in a new window] ,
M. Scheffler ,
F. D. S. Simonsen Open the ORCID record for F. D. S. Simonsen [Opens in a new window] ,
P. A. Jensen  and
L. Hornekær
J. D. Thrower
Affiliation:
Department of Physics & Astronomy, Aarhus University, 8000 Aarhus C, Denmark email: thrower@phys.au.dk
G. Pantazidis
Affiliation:
Department of Physics & Astronomy, Aarhus University, 8000 Aarhus C, Denmark email: thrower@phys.au.dk
M. Scheffler
Affiliation:
Department of Physics & Astronomy, Aarhus University, 8000 Aarhus C, Denmark email: thrower@phys.au.dk
F. D. S. Simonsen
Affiliation:
Department of Physics & Astronomy, Aarhus University, 8000 Aarhus C, Denmark email: thrower@phys.au.dk
P. A. Jensen
Affiliation:
Department of Physics & Astronomy, Aarhus University, 8000 Aarhus C, Denmark email: thrower@phys.au.dk
L. Hornekær
Affiliation:
Department of Physics & Astronomy, Aarhus University, 8000 Aarhus C, Denmark email: thrower@phys.au.dk Interdisciplinary Nanoscience Center (iNANO), Aarhus University, 8000 Aarhus C, Denmark email: liv@phys.au.dk
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Abstract

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Experimental evidence for the formation of hydrogenated fullerene molecules is presented. Films of C60 were grown on a highly oriented pyrolytic graphite (substrate) and exposed to a beam of deuterium atoms. Thermal desorption combined with mass spectrometry was used to determine the deuterated fullerene products formed, revealing a maximum degree of deuteration corresponding to C60D36. Release of D2 from the deuterated C60 film occurs at a much higher temperature than for D-saturated graphite.

Keywords

physical data and processes: astrochemistrymethods: laboratoryISM: moleculesISM: clouds

Footnotes

†

Present address: School of Engineering and Natural Sciences, University of Iceland, Reykjavík, Iceland

References

Berné, O. & Tielens, A. G. G. M. 2012, PNAS, 109, 401 CrossRefGoogle Scholar
Berné, O., Mulas, G., & Joblin, C. 2013, A&A(Letters), 550, L4 CrossRefGoogle Scholar
Berné, O., Montillaud, J., & Joblin, C. 2015, A&A, 577, A133 Google Scholar
Berné, O., Cox, N. L. J., Mulas, G., & Joblin, C. 2017, A&A, 605, L1 Google Scholar
Boschmann, L., Reitsma, G., Cazaux, S., Schlathölter, T., Hoekstra, R., Spaans, M., & González-Magaña, O. 2012, ApJL, 761, L33 CrossRefGoogle Scholar
Cami, J., Bernard-Salas, J., Peeters, E., & Malek, S. E. 2010, Science, 329, 1180 CrossRefGoogle Scholar
Campbell, E. K., Holz, M., Gerlich, D., & Maier, J. P. 2015, Nature, 523, 322 CrossRefGoogle Scholar
Cazaux, S., Boschmann, L., Rougeau, N., Reitsma, G., Hoekstra, R., Teillet-Billy, D., Morisset, S., Spaans, M., & Schlathölter, T. 2016, Sci. Rep., 6, 19835 CrossRefGoogle Scholar
Clare, B. W. & Kepert, D. L. 2003, Theo. Chem., 622, 185 Google Scholar
Foing, B. H. & Ehrenfreund, P. 1994, Nature, 369, 296 CrossRefGoogle Scholar
Güttler, A., Zecho, T., & Küppers, J. 2004, Surf. Sci., 570, 218 CrossRefGoogle Scholar
Habart, E., Boulanger, F., Verstraete, L., Pineau des Forê ts, G., Falgarone, E., & Abergel, A. 2003, A&A, 397, 623 Google Scholar
Habart, E., Boulanger, F., Verstraete, L., Walmsley, C. M., & Pineau des Forê ts, G. 2004, A&A, 414, 531 Google Scholar
Hornekær, L., S Šljivan c Šanin, Z Ž., Xu, W., Otero, R., Rauls, E., Stensgaard, I., Lægsgaard, E., Hammer, B., & Besenbacher, F. 2006, Phys. Rev. Lett., 96, 156104 CrossRefGoogle Scholar
Jensen, P. A., Leccesse, M., Simonsen, F. D. S., Skov, A. W., Bonfanti, M., Thrower, J. D., Martinazzo, R., & Hornekæ r, L. 2019, MNRAS, 486, 5492 CrossRefGoogle Scholar
Löffler, D., Weis, P., Böttcher, A., & Kappes, M. 2007, J. Phys. Chem. C, 111, 17743 CrossRefGoogle Scholar
Mennella, V., Hornekæ r, L., Thrower, J., & Accolla, M. 2012, ApJL, 745, L2 CrossRefGoogle Scholar
Palit, D. K., Mohan, H., & Mittal, J. P. 2008, J. Phys. Chem. A, 102, 4456 CrossRefGoogle Scholar
Rauls, E. & Hornekæ r, L. 2008, ApJ, 679, 531 CrossRefGoogle Scholar
Sellgren, K., Werner, M. W., Ingalls, J. G, Smith, J. D. T, Carleton, T. M & Joblin, C 2010, ApJL, 722, L54 CrossRefGoogle Scholar
Tielens, A. G. G. M. 2013, Rev. Mod. Phys., 85, 1021 CrossRefGoogle Scholar
Tschersich, K. G. 2000, J. Appl. Phys., 87, 2565 CrossRefGoogle Scholar
Thrower, J. D, Jø rgensen, B., Friis, E., Baouche, S., Luntz, A. C., Andersen, M., Hammer, B., & Hornekæ r, L. 2012, ApJ, 752, 3 CrossRefGoogle Scholar
Zhen, J., Castellanos, P., Paardekooper, D. M., Linnartz, H., & Tielens, A. G. G. M. 2014, ApJL, 797, L30 CrossRefGoogle Scholar