Hostname: page-component-6587cd75c8-4pd2k Total loading time: 0 Render date: 2025-04-23T22:39:41.500Z Has data issue: false hasContentIssue false
  • English
  • Français

X-ray powder diffraction data for three new compounds obtained as a result of CO2 capture

Published online by Cambridge University Press:  23 November 2023

Klaudia Nowakowska Open the ORCID record for Klaudia Nowakowska [Opens in a new window]  and
Wiesław Łasocha Open the ORCID record for Wiesław Łasocha [Opens in a new window]
Klaudia Nowakowska
Affiliation:
Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland
Wiesław Łasocha*
Affiliation:
Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland Jerzy Haber Institute of Catalysis and Surface Chemistry PAS, Niezapominajek 8, 30-239 Krakow, Poland
*
a)Author to whom correspondence should be addressed. Electronic mail: lasocha@chemia.uj.edu.pl
Get access Rights & Permissions [Opens in a new window]

Abstract

The field of research related to CO2 capture is significant and really attractive for sustainable green chemistry. Focusing attention on this topic in our research led to obtaining new compounds based on diamines. As a result of the syntheses carried out using aqueous solutions of diamines exposed to the slow action of carbon dioxide from the air, three new monocarbamates were obtained. X-ray powder diffraction data for the obtained compounds: 12-propCO2 (C4H10N2O2) [a = 9.3033(7), b = 9.2485(7), c = 7.4735(7) Å, β = 111.214(7)°, V = 599.46 Å3, Z = 4, space group Ia]; 13-propCO2 (C4H10N2O2) [a = 5.0065(10), b = 12.2093(23), c = 4.9006(10) Å, β = 96.457(18)°, V = 297.65 Å3, Z = 2, space group P21]; and 13-dytekCO2 (C6H14N2O2) [a = 28.374(3), c = 5.1726(9) Å, V = 3606.53 Å3, Z = 18, space group $R\bar{3}$] are reported in this paper.

Keywords

carbamateCO2 capturealiphatic aminesX-ray diffraction
Type
New Diffraction Data
Information
Powder Diffraction , Volume 38 , Issue 4 , December 2023 , pp. 253 - 258
Check for updates
Copyright
Copyright © The Author(s), 2023. Published by Cambridge University Press on behalf of International Centre for Diffraction Data

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENES

Altomare, A., Cuocci, C., Giacovazzo, C., Moliterni, A., Rizzi, R., Corriero, N., and Falcicchio, A.. 2013. “EXPO2013: A Kit of Tools for Phasing Crystal Structures from Powder Data.” Journal of Applied Crystallography 46 (4): 1231–35. doi:10.1107/S0021889813013113.CrossRefGoogle Scholar
Degen, T., Sadki, M., Bron, E., König, U., and Nénert, G.. 2014. “The HighScore Suite.” Powder Diffraction 29 (S2): S13–18. doi:10.1017/S0885715614000840.CrossRefGoogle Scholar
De Wolf, P. M. 1968. “A Simplified Criterion for the Reliability of a Powder Pattern Indexing.” Journal of Applied Crystallography 1 (2): 108–13. doi:10.1107/S002188986800508X.CrossRefGoogle Scholar
Gates-Rector, S., and Blanton, T.. 2019. “The Powder Diffraction File: A Quality Materials Characterization Database.” Powder Diffraction 34 (4): 352–60. doi:10.1017/S0885715619000812.CrossRefGoogle Scholar
Gonzalez, G. A., Oszajca, M., Luberda-Durnaś, K., and Lasocha, W.. 2019. “Synthesis, Crystal Structure Solution and Characterization of Two Organic–Inorganic Hybrid Layered Materials Based on Metal Sulfates and 1,4-Phenylenediamine.” Acta Crystallographica Section C Structural Chemistry 75 (11): 1502–8. doi:10.1107/S205322961901180X.CrossRefGoogle Scholar
Leszczyński, M. K., Kornacki, D., Terlecki, M., Justyniak, I., Miletic, G. I., Halasz, I., Bernatowicz, P., Szejko, V., and Lewiński, J.. 2022. “Mechanochemical Vs Wet Approach for Directing CO2 Capture Toward Various Carbonate and Bicarbonate Networks.” ACS Sustainable Chemistry Engineering 10 (14): 4373–80. doi:10.1021/acssuschemeng.1c08402.CrossRefGoogle ScholarPubMed
Luberda-Durnaś, K., Gaweł, B., Łoś, M., and Łasocha, W.. 2011. “Synthesis and Characterization of Inorganic-Organic ZnS(Aminopropane)n Composite Materials.” Crystal Research and Technology 46 (12): 1283–90. doi:10.1002/crat.201100380.CrossRefGoogle Scholar
Smith, G. S., and Snyder, R. L.. 1979. “FN: A Criteria for Rating Powder Diffraction Patterns and Evaluating the Reliability of Powder-Pattern Indexing.” Journal of Applied Crystallography 12 (1): 60–65. doi:10.1107/S002188987901178XCrossRefGoogle Scholar
Zhou, H., Shi, F., Tian, X., Zhang, Q., and Deng, Y.. 2007. “Synthesis of Carbamates from Aliphatic Amines and Dimethyl Carbonate Catalyzed by Acid Functional Ionic Liquids.” Journal of Molecular Catalysis A: Chemical 271 (1–2): 89–92. doi:10.1016/j.molcata.2007.02.017.CrossRefGoogle Scholar
Supplementary material: File

Nowakowska and Łasocha supplementary material 1

Nowakowska and Łasocha supplementary material
Download Nowakowska and Łasocha supplementary material 1(File)
File 10.7 KB
Supplementary material: File

Nowakowska and Łasocha supplementary material 2

Nowakowska and Łasocha supplementary material
Download Nowakowska and Łasocha supplementary material 2(File)
File 16.1 KB
Supplementary material: File

Nowakowska and Łasocha supplementary material 3

Nowakowska and Łasocha supplementary material
Download Nowakowska and Łasocha supplementary material 3(File)
File 10.2 KB