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An X-ray diffraction study of pyrolytic manganese dioxide

Published online by Cambridge University Press:  10 January 2013

K. D. Rogers  and
D. Cossins
K. D. Rogers
Affiliation:
Cranfield Institute of Technology (RMCS), Shrivenham, Swindon, Wiltshire SN6 8LA, United Kingdom
D. Cossins
Affiliation:
A.V.X. Ltd (Tantalum Division), Long Road, Paignton, Devon, United Kingdom
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Abstract

The thermal decomposition of aqueous manganese nitrate has been studied under a range of experimental conditions to scientifically assess the pyrolysis processes employed by the tantalum capacitor industry. The crystalline phase and form of the manganese oxides produced are compared by X-ray diffraction and scanning electron microscopy. Those experimental conditions producing materials with the lowest resistivity are identified. The technological significance of the decomposition process is discussed and initial results from a novel pyrolysis technique are presented.

Information

Type
Research Article
Information
Powder Diffraction , Volume 8 , Issue 1 , March 1993 , pp. 18 - 24
Copyright
Copyright © Cambridge University Press 1993

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References

Albella, J. M., Navarrete, L. F., and M-Duart, J. M. (1981). J. Appl. Electrochem. 11, 273–279.CrossRefGoogle Scholar
Bandurek, G. R., Disney, J., and Bendell, A. (1988). Qual. and Rel. Eng. Int. 4, 171–181.CrossRefGoogle Scholar
Baur, W. (1976). Acta. Cryst. B32, 2200–2204.Google Scholar
Bish, D. L., and Howard, S. A. (1988). J. Appl. Cryst. 21, 86–91.CrossRefGoogle Scholar
De Bruijn, T. J., de Jong, W. A., and Van Den Berg, P. J. (1981a). Thermochim. Acta. 45, 265–278.CrossRefGoogle Scholar
De Bruijn, T. J., de Ruiter, G. M. J., de Jong, W. A., and Van Den Berg, P. J. (1981b). Thermochim. Acta. 45, 279–292.Google Scholar
Burns, V. M., and Burns, R. G. (1975). Manganese Dioxide Symposium 1, Papers 15, 16, 228–306, I. C. Sample Office, Cleveland.Google Scholar
Desai, B. D., Dhume, R. A. S., and Dalal, V. N. K. (1988). J. Appl. Electrochem. 18, 62–74.Google Scholar
Euler, K-J. (1979). J. Appl. Electrochem. 9, 395.CrossRefGoogle Scholar
Fernandes, J. B., Desai, B. D., and Delal, V. N. K. (1985). J. Power Sources 15, 209–237.CrossRefGoogle Scholar
Gallagher, P. K., and Johnson, D. W. (1971a). Thermochim. Acta. 2, 405.Google Scholar
Gallagher, P. K., and Johnson, D. W. (1971b). J. Electrochem. Soc. 118, 1530.CrossRefGoogle Scholar
Giovanoli, R. (1985). Chem. Erde 44, 227–244.Google Scholar
Glemser, O., and Meisiek, H. (1958). J. Prakt. Chem. 5, 219–224.Google Scholar
Hong, L., Zhen-hai, C., and Xi, X. (1988). Prog. Batteries Solar Cells 7, 82–95.Google Scholar
Hunter, J. C. (1981). J. Sol. Stat. Chem. 39, 142–147.CrossRefGoogle Scholar
Langton, A. J., and James, A. J. (1967). STC Technical Report 41/1967/361.Google Scholar
Lundquist, R. V. (1957). US Bur. Mines Rep. Invest. 5347.Google Scholar
Maskell, W. C., Shaw, J. A. E., and Tye, F. L. (1982). J. Appl. Electrochem. 12, 101–108.CrossRefGoogle Scholar
Montoliu, F. C., Font, R. C., and Munoz, E. G. (1985a). Anales de Quimica 82, 261–265.Google Scholar
Montoliu, F. C., Font, R. C., and Munoz, E. G. (1985b). Anales de Quimica 82, 264–267.Google Scholar
Morita, M., Iwakura, C., and Tamura, H. (1977). Electrochem. Acta. 22, 325–328.CrossRefGoogle Scholar
Mourad, W. E., Rophael, M. W., and Khalil, L. B. (1980). J. Appl. Electrochem. 10, 309–313.Google Scholar
McBreen, J. (1975). 1st Manganese Dioxide Symposium, Cleveland 97.Google Scholar
McMurdie, H. F., and Golovato, E. (1948). NBS Research Paper RP1941 41, 589–600.Google Scholar
Nye, W. F., Levin, S. B., and Kedesdy, H. M. (1959). Proc. 13th Annual Power Sources Conf. April 125–129.Google Scholar
Preisler, E. (1976). J. Appl Electrochem. 6, 311.Google Scholar
Rogers, D. B., Shannon, R. D., Sleight, T. P., and Gillson, R. (1969). Inorganic Chem. 8, 845.CrossRefGoogle Scholar
Sasaki, K., and Kojima, K. (1954). J. Electrochem. Soc. Jap. 22, 564.Google Scholar
Sutton, W. H. (1989). Ceramic Bulletin 68, 376–386.Google Scholar
Wiley, J. S., and Knight, H. T. (1964). J. Electrochem. Soc. 111, 656–660.Google Scholar
Wolff, P. M., Visser, J. W., Giovanoli, R., and Brütsch, R. (1978). Chimia 32, 257–259.Google Scholar
Yoshida, A., and Nishino, A. (1989). Denki Kagaku 57, 408–415.Google Scholar