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The Use of Functionalized Polybenzoxazoles and Polybenzobisthiazoles in Polymer-Silica Hybrid Materials

Published online by Cambridge University Press:  10 February 2011

J. E. Mark ,
J. Premachandra ,
C. Kumudinie ,
W. Zhao ,
T. D. Dang ,
J. P. Chen  and
F. E. Arnold
J. E. Mark
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
J. Premachandra
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
C. Kumudinie
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
W. Zhao
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
T. D. Dang
Affiliation:
Wright Laboratory, Materials Directorate, Wright-Patterson Air Force Base, Dayton, OH 45433
J. P. Chen
Affiliation:
Wright Laboratory, Materials Directorate, Wright-Patterson Air Force Base, Dayton, OH 45433
F. E. Arnold
Affiliation:
Wright Laboratory, Materials Directorate, Wright-Patterson Air Force Base, Dayton, OH 45433
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Abstract

Hybrid organic-inorganic composites were prepared by precipitating silica into hydroxypolybenzoxazole (HPBO) and sulfopolybenzobisthiazole (SPBT) polymers, with interfacial bonding between the phases improved by use of isocyanatopropyltriethoxy silane and N,N-diethylaminopropyltrimethoxy silane, respectively. The resulting materials were characterized with regard to their transparency, silica particle distribution, tensile modulus and tensile strength, thermal stability, and tendency to absorb water.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 93
Copyright
Copyright © Materials Research Society 1996

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