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The Synthesis of Transition Metal Sulfides and Sulfo-Salt Crystals in Hydrothermal Brines

Published online by Cambridge University Press:  15 February 2011

J. W. Kolis  and
M. B. Korzenski
J. W. Kolis
Affiliation:
Department of Chemistry, Clemson University, ClemsonSC 29634, KJOSEPH@Clemson.edu
M. B. Korzenski
Affiliation:
Department of Chemistry, Clemson University, ClemsonSC 29634, KJOSEPH@Clemson.edu
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Abstract

A new procedure for the synthesis of transition metal sulfosalts in hydrothermal brines is presented. Large, well formed crystals of metal antimony sulfides can be prepared under appropriate conditions in supercritical brines. A new compound prepared by this method, MnSb2S4, is structurally characterized.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 453: Symposium R – Solid State Chemistry of Inorganic Materials , 1996 , 35
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Schimek, G.L., Pennington, W.T., Wood, P. T., Kolis, J.W., J Solid State Chemistry 123, 277 (1996).Google Scholar
2. Wood, P.T., Schimek, G.L., Kolis, J.W., Chem. Mater. 8, 721, (1996).Google Scholar
3. Wood, P.T., Pennington, W.T., Kolis, J.W., Inorg. Chem. 33, 1556 (1994).Google Scholar
4. Wood, P.T., Pennington, W.T., Kolis, J.W., J.W. J.Am. Chem. Soc. 114, 9233 (1992).Google Scholar
5. Young, D. M., Schimek, G. L., Kolis, J. W., Inorg. Chem. in press.Google Scholar
6. Hubert L., Barnes Geochemistry of Hydrothermal Ore Deposits 2nd Ed., John Wiley and Sons, New York, 1979.Google Scholar
7. Barnes, H.L., Czamanske, G.K., in Geochemistry of Hydrothermal Ore Deposits 1 st Ed., edited by Barnes, H.L., Holt Reinhardt and Winston, New York, 1967, p. 334.Google Scholar
8. Helgesen, H.C., Complexing and Hydrothermal Ore Deposition, Pergamon Press, Oxford, 1964.Google Scholar
9. Crerar, D.A., Barnes, H.L., Econ. Geol. 71, 772 (1976).Google Scholar
10. Ulmer, G.C., Barnes, H.L., Hydrothermal Experimental Techniques, Wiley-Interscience, New York, 1987.Google Scholar
11. See ref. 2 for typical solutions of single crystal structures in our labs.Google Scholar
12. Popolitov, V.l., Litvin, B.N., in Crystallization Processes under Hydrothermal Conditions, edited by Lobachev, A.N., Consultants Bureau, New York, 1973, p 73.Google Scholar
13. Skinner, B.J., Luce, F.D., Mackovicky, E., Econ. Geol. 72, 924 (1972).Google Scholar
14. Beurger, M.J., Hahn, T. Am. Mineral. 40, 226 (1955).Google Scholar
15. Wintenberger, M., Andre, G., Physica B 162, 5 (1990)Google Scholar
16. Coucouvanis, D., Patii, P.R., Kanatzidis, M.G., Detering, B., N.C. Baenziger Inorg. Chem. 24, 24, (1985).Google Scholar
17. Wells, A.F., Structural Inorganic Chemistry 5th Ed. Clarendon Press, Oxford, 1984, p.759.Google Scholar