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Synthesis of a Novel Donor, BTFE-DMB, and Electrical Properties of its Iodine Salt

Published online by Cambridge University Press:  25 February 2011

Makoto Mizutani ,
Keiji Tanaka ,
Kiyoshi Ikeda  and
Kazushige Kawabata
Makoto Mizutani
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
Keiji Tanaka
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
Kiyoshi Ikeda
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
Kazushige Kawabata
Affiliation:
Central Research Laboratories, Idemitsu Kosan Co., Ltd. 1280 Kamiizumi, Sodegaura, Chiba 299–02, Japan.
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Abstract

1, 4-Bis [2-(tetrathiafulvalen-2-yl)ethenyl] -2, 5-dimethylbenzene (BTFE-DMB) is synthesized and its structure is found to be planar. The single crystal of its iodine salts undergoes a metal-insulator transition about 180K. The compaction pellets of the iodine salts show the current dependent resistive anomaly under high pressure.

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References

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