Hostname: page-component-54dcc4c588-b5cpw Total loading time: 0 Render date: 2025-09-21T19:21:53.916Z Has data issue: false hasContentIssue false
  • English
  • Français

Studies of the Initial Steps in Sol-Gel Processing of Si(OR)4:29Si NMR of Alkoxysilane and Alkoxysiloxane Solutions

Published online by Cambridge University Press:  28 February 2011

Carol A. Balfe  and
Sheryl L. Martinez
Carol A. Balfe
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
Sheryl L. Martinez
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
Get access

Abstract

Silicon-29 NMR has been used to investigate the initial steps of hydrolysis and condensation of tetramethoxysilane (TMOS), hexamethoxydisiloxane, and octamethoxytrisiloxane in both basic and acidic methanol solutions. Comparisons of the spectra obtained from the various starting solutions and literature reports of mono-, di-, and tri-silicic acids in aqueous solution were used to identify and assign chemical shifts to condensation intermediates in the TMOS system. The observation of cyclic intermediates in the acid catalysis of TMOS in methanol and the chemical shifts of several products of its hydrolysis and condensation are reported.

Information

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 73: Symposium H – Better Ceramics Through Chemistry II , 1986 , 27
Copyright
Copyright © Materials Research Society 1986

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1. Voronkov, M. G., Zhagata, L. A., Zh. Obschei Khimii, 37, 2764 (1976).Google Scholar
2. Fletcher, H. J., Hunter, M. J., J. Amer. Chem. Soc., 71, 2922 (1949).Google Scholar
3. Sprung, M. M., Guenther, F. O., J. Amer. Chem. Soc., 77, 4173 (1955).CrossRefGoogle Scholar
4. Sprung, M. M., Guenther, F. O., J. Amer. Chem. Soc., 77, 6054 (1955).Google Scholar
5. Aelion, R., Loebbel, A., Eirich, F., J. Amer. Chem. Soc., 72, 5705 (1950).Google Scholar
6. Engelhardt, V. G., Altenburg, W., Hoebbel, D. and Wieker, W., Anorg, Z., Allg. Chem., 428, 43 (1977).Google Scholar
7. Hoebbel, D., Garzo, G., Engelhardt, G., and Till, A., Z. Anorg. Allg. Chem., 450, 5 (1979).Google Scholar
8. Klemperer, W. G., Mainz, V. V., Millar, D., U. of Illinois Chem. Dept., Manuscript in preparation.Google Scholar
9. Engelhardt, G., Jancke, H., Hoebbel, D., and Wieker, W., Z. Chem., 14, 109 (1974).Google Scholar
10. Marsmann, H. C., Meyer, E., Vongehr, M., Weber, E. F., Makromol. Chem., 184, 1817 (1983).Google Scholar
11. Engelhardt, V. G., Altenburg, W., Hoebbel, D., and Wieker, W., Z. Anorg. Allg. Chem., 437, 249 (1977).Google Scholar
12. Artaki, I., Bradley, M., Zerda, T. W., and Jonas, J., J. Phys. Chem., 89, 4399 (1985).Google Scholar