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Studies in The Organic Solid State

Published online by Cambridge University Press:  16 February 2011

George M. Whitesides ,
Jonathan A. Zerkowski ,
John C. MacDonald  and
Donovan Chin
George M. Whitesides
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
Jonathan A. Zerkowski
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
John C. MacDonald
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
Donovan Chin
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
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Abstract

This paper describes an approach to crystal engineering based on designing and analyzing hierarchical levels of crystalline architecture. The system under study consists of 1:1 co-crystals of melamines and barbituric acids that self-assemble into crystallographically infinite hydrogen-bonded tapes. The formation of structural elements can be rationalized and controlled using familiar molecular concepts such as steric repulsion.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 3
Copyright
Copyright © Materials Research Society 1994

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References

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