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Published online by Cambridge University Press: 10 February 2011
The low-temperature (5K) photoluminescence (PL) of partially-ordered GaInP2 is spatially resolved using high-resolution (from ˜ 0.2μm-0.7μm) scanning optical microscopy, revealing the spatial variation in band gap energy and the spatial origin of the ordering-induced low-energy emission and the associated ‘quantum-dot-like’ narrow spikes which appear when examining areas smaller, or of comparable size, than a single ordered domain. The large number of spectra taken within a micronsized area allow a detailed look at the statistical variation in band-gap energy and lineshape. A systematic study of a series of samples where the order parameter varies from η ˜ 0 to 0.45 shows that for the most highly-ordered samples, the statisitical distribution of excitonic energy and linewidth show evidence of exciton localization, which is also clearly seen by examining the spatial maps of the excitornic energy and linewidth extracted from the measured spectra.