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Sequence-Controlled Vinyl Polymers by Transition Metal-Catalyzed Step-Growth and Living Radical Polymerizations

Published online by Cambridge University Press:  06 February 2014

Kotaro Satoh  and
Masami Kamigaito
Kotaro Satoh
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, 464-8603, Japan
Masami Kamigaito
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, 464-8603, Japan
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Abstract

The metal-catalyzed step-growth radical polymerization was achieved to enable two systems for preparing tailored polymeric structures, i.e., sequence-regulated vinyl copolymer and periodically-functionalized polymer. The former is a novel strategy for preparing sequence-regulated vinyl copolymers by step-polymerization of sequence-regulated vinyl oligomers prepared from common vinyl monomers as building blocks. The later deals the simultaneous chain- and step-growth radical polymerization, which resulted in the polymers with periodic functional groups.

Keywords

polymerpolymerizationchemical synthesis
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1613: Symposium 4D – New Trends in Polymer Chemistry and Characterization-2013 , 2014 , pp. 17 - 21
Copyright
Copyright © Materials Research Society 2014 

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References

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