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Self-Assembly of Cobalt/Bipyridine Multilayers Modeled After Hofmann Clathrate Compounds

Published online by Cambridge University Press:  15 February 2011

Michael A. Ansell ,
Astrid C. Zeppenfeld ,
William K. Ham  and
Catherine J. Page
Michael A. Ansell
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403
Astrid C. Zeppenfeld
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403
William K. Ham
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403
Catherine J. Page
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403
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Abstract

Progress has been made towards the development of inorganic-organic multilayered films modeled after Hofmann clathrate compounds. Cobalt-bipyridine multilayers were grown layer by layer on a silicon substrate. The resulting films were characterized using ellipsometry, grazing angle X-ray diffraction, Auger electron spectroscopy and EPMA (Electron Probe Micro- Analysis). Results indicate that moderately well ordered layers have been synthesized, but cross-linking with M(CN)42(M = Ni, Pd, or Pt) to simulate the model structure does not significantly occur.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 351: Symposium V – Molecularly Designed Ultrafine/Nanostructured Materials , 1994 , 171
Copyright
Copyright © Materials Research Society 1994

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