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Research on Computer Optimization of Low-Cost Hydrogen Storage Alloy Containing Boron Prepared by Strip Casting and its Microstructure and Performance

Published online by Cambridge University Press:  26 February 2011

Hong Guo ,
Han Weiping ,
Zhang Ximin  and
Shi Likai
Hong Guo
Affiliation:
guohong@mail.grinm.com.cn, Generral Research Institute for Non-ferrous Metal, Composite Center, No.2, Xinjiekou Wai Street, Xicheng District, Beijing, 100088, China, People's Republic of
Han Weiping
Affiliation:
hanweiping@atmcn.com, Beijing General Research Institute for Non-ferrous Metals, Beijing, 100088, China, People's Republic of
Zhang Ximin
Affiliation:
zxm1214@sohu.com, Beijing General Research Institute for Non-ferrous Metals, Beijing, 100088, China, People's Republic of
Shi Likai
Affiliation:
shilikai@mail.grinm.com.cn, Beijing General Research Institute for Non-ferrous Metals, Beijing, 100088, China, People's Republic of
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Abstract

A kind of low-cost hydrogen storage alloy containing B has been prepared by near rapid solidification strip casting. And computer optimization has been carried out with MASTER software through mode identification and neuro-network. The alloy microstructure, the alloy performance and the battery performance have been evaluated through optical microscope, TEM and X-ray diffraction. The results indicate that the alloy microstructure is fine columnar crystal and there exists the second phase of CeCo4B on the crystal interface, which increases the diffusion channels for hydrogen atoms and improves the alloy activation. The MmNi3.9Co0.37Mn0.4Al0.3B alloy has excellent performance at room, high and low temperatures prepared by strip casting.

Keywords

alloyabsorptionmicrostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 971: Symposium Z – Hydrogen Storage Technologies , 2006 , 0971-Z07-04
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

[1] Willems, J. J. G., Buschow, K. H. J., J. Less-Common Metals 129 (1987) pp.13–16 Google Scholar
[2] Hu, W. K., J. Alloys Comp. 289 (1999) pp.299ñ305.Google Scholar
[3] Li, Q. A., Sang, G., Li, J.W., Chen, Y.G., Tu, M.J., J. Chin. Rare Earths 21 (4) (2000)pp. 30ñ33.Google Scholar
[4] Wang, Z. X., Li, X. H., Chen, Q. Y., Guo, B. K., Guo, H. J., Peng, W. J., J. Chin. Rare Earths Soc. 18 (3) (2000)pp. 226ñ228.Google Scholar
[5] Hu, W. K., Lee, H., Kim, D.M., Jeon, S.W., Lee, J.Y., J. Alloys Comp. 268 (1998)pp. 261–265 Google Scholar
[6] Ye, H., Huang, Y. X., Huang, T. S., Zhang. J Alloys Comp. 330–332 (2002)pp.866–870 Google Scholar
[7] Buschow, K. H., Van, H. H., Mal, H. H.. J Less-common Met, 203(1972)pp.29–35 Google Scholar
[8] Jing, H., Guo, H., Zhu, X. X., Ma, Z. L., et al. J Rare metal., 28(1) (2000) pp.243–247 Google Scholar
[9] Ye, H., Zhang, H.. J Electrochemical Soc., 149 (2002)pp.122–126 Google Scholar