Hostname: page-component-cb9f654ff-nr592 Total loading time: 0 Render date: 2025-09-10T20:10:22.415Z Has data issue: false hasContentIssue false
  • English
  • Français

Raman and Surface Enhanced Raman Spectroscopy of Titanium Carboxylates

Published online by Cambridge University Press:  25 February 2011

Beatrice A. Van Vlierberge-Torgerson ,
Dilum Dunuwila  and
Kris A. Berglund
Beatrice A. Van Vlierberge-Torgerson
Affiliation:
Michigan State University, Departments of Chemical Engineering and Agricultural Engineering, East Lansing, MI 48824, USA.
Dilum Dunuwila
Affiliation:
Michigan State University, Departments of Chemical Engineering and Agricultural Engineering, East Lansing, MI 48824, USA.
Kris A. Berglund
Affiliation:
Michigan State University, Departments of Chemical Engineering and Agricultural Engineering, East Lansing, MI 48824, USA.
Get access

Abstract

Porous stable metal-organic films can be processed under mild conditions by the hydrolysis of carboxylic acid and titanium isopropoxide mixtures. It is of importance to establish the structure of such materials. Raman spectroscopy is a useful technique in determining structural changes in titanium isopropoxide carboxylate solutions, but weak scattering does not allow for study of thin films unless surface enhancement is used. In an attempt to elucidate the relationship between coating solutions and the final structure of a cast film, we discuss Raman spectra of precursor solutions in a variety of conditions.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 65
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1- Sanchez, C. and Livage, J., New J. Chem. 14, 513 (1990).Google Scholar
2- Hubert-Pfalzgraf, L. G., New J. Chem., 11, 663 (1987).Google Scholar
3- Bradley, D. C., Mehrotra, R. C. and Gaur, D. P., Metal Alkoxides, (Academic Press, New York, 1978).Google Scholar
4- Pande, K. C. and Mehrotra, R. C., Z. Anorg. Alllg. Chemie, 291, 97 (1958).CrossRefGoogle Scholar
5- Pande, K. C. and Mehrotra, R. C., Z. Anorg. Alllg. Chemie, 290, 87 (1957).CrossRefGoogle Scholar
6- Dunuwila, D., Gagliardi, C. D. and Berglund, K. A., unpublished results.Google Scholar
7- Lessard, R. B., Wallace, M. M., Oertling, W. A., Chang, C. K., Berglund, K. A. and Nocera, D. G., in Processing Science of Advanced Ceramics, ed. by Aksay, I. A., McVay, G. L. and Ulrich, D. R. (Mat. Res. Soc. Proc. 155, Pittsburgh, PA, 1989) pp. 109–117.Google Scholar
8- Dulebohn, J. I., Van Vlierberge, B. A., Berglund, K. A., Lessard, R. B., Yu, J. and Nocera, D. G., in Better Ceramics through Chemistry IV, ed. by Zelinsky, B.J.J., Brinker, C.J., Clark, D.E. and Ulrich, D.R. (Mat. Res. Soc. Proc. 180, Pittsburgh, PA, 1990) pp. 733–740.Google Scholar
9- Ni, F. and Cotton, T. M., Anal. Chem. 58, 3159 (1986).CrossRefGoogle Scholar
10- Zietler, V. A. and Brown, C. A., J. Phys. Chem, 61, 1174 (1957).CrossRefGoogle Scholar
11- Barraclough, C. G., Bradley, D. C., Lewis, J. and Thomas, I.M., J. Chem. Soc 1961 2601.CrossRefGoogle Scholar
12- Mehrotra, R. C. and Bohra, R., Metal Carboxylates, (Academic Press, New York 1983), pp. 48–60 and 233–240.Google Scholar
13- Nakamoto, K., IR and Raman Spectra of Inorganic and Coordination Compounds (Wiley and Sons publishers, New York, 1986), pp. 231–233.Google Scholar
14- Gagliardi, C. D., Dunuwila, D. and Berglund, K. A., in Better Ceramics through Chemistry, IV, ed. by Zelinsky, B. J. J., Brinker, C. J., Clark, D. E. and Ulrich, D. R. (Mat. Res. Soc. Proc. 73 Pittsburgh, PA, 1990) pp. 801–805.Google Scholar
15- Payne, M. J. and Berglund, K. A., in Better Ceramics through Chemistry, (Mat. Res. Soc. Proc. 23., Pittsburgh, PA, 1986) pp. 627–631.Google Scholar
Berglund, K. A., Tallant, D. R., and Dosch, R. G., in Ultrastructure Processing of Ceramics. Glasses and Composites, ed. by Hench, L. L. and Ulrich, D. R. (Wiley, New York, 1985), pp. 94–99.Google Scholar
16- Amaudrut, J., Bull. Soc. Chim, 7–8, 624 (1977).Google Scholar
17- Severin, K. (private communication).Google Scholar
18- Van Vlierberge-Torgerson, B. A., Dulebohn, J. I. and Berglund, K. A., Chemical Processing of Advanced Materials, ed. by Hench, L. L. (Wiley, & Sons New York, in press).Google Scholar