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Preparation of Phenylsiloxane Films VIA Solution Deposition Techniques

Published online by Cambridge University Press:  28 February 2011

E.W. Burkhardt
Affiliation:
Akzo Chemicals Inc., Livingstone Ave., Dobbs Ferry, NY 10522
R.R. Burford
Affiliation:
Chisholm Institute of Technology, Department of Chemistry, East Caulfield, Victoria, Australia, 3145
J.H. Deatcher
Affiliation:
Akzo Chemicals Inc., Livingstone Ave., Dobbs Ferry, NY 10522
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Abstract

Thin films (1–10μ thick) can be spin coated on a variety of substrates from formulations containing polyphenylsiloxanes and alkylsilicates. These films may be cured either thermally or photochemically, yielding films with good adherence to the substrate. The combination of photolysis and thermolysis results in changes in the film hardness characteristics. The use of a mask during photocuring results in films which may be developed in either a positive or negative fashion. The preparation of various formulations along with film curing processes will be discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Estes, W.E. and Marsh, W.E., U.S. Patent No. 4 663 414 (5 May 1987).Google Scholar
2. Whitwell, G.E. and Deatcher, J.H., U.S. Patent No. 4 758 620 (19 July 1988).Google Scholar
3. Estes, W.E., Deatcher, J.H., Whitwell, G.E.,U.S. Patent No. 4 801 507 (31 January 1989).Google Scholar
4. Schmidt, H. in Better Ceramics Through Chemistry, edited by Brinker, C.J., Clark, D.E., and Ulrich, D.R. (Mater. Res. Soc. Proc. 32, Albuquerque, NM 1984) pp. 327335.Google Scholar
5. Schmidt, H. and Seiferling, B. in Better Ceramics Through Chemistry II, edited by Brinker, C.J., Clark, D.E., and Ulrich, D.R. (Mater. Res. Soc. Proc. 73, Palo Alto, CA 1986) pp. 739750;Google Scholar
5a. Parkhurst, C.S., Doyle, W.F., Silverman, L.A., Singh, S., Andersen, M.P., McClurg, D., Wnek, G.E. and Uhlmann, D.R., ibid., pp.769773.Google Scholar
6. Burns, H.D., Whitaker, A.F. and Linton, R.C., Surface and Coatings Tech. 39/40, 627 (1989).Google Scholar
7. Hundley, N.H. and Patterson, W.J., NASA Technical Paper 2476[N8526990/NSP].Google Scholar
8. Arnold, C.A., Chen, D., Chen, Y.P., Graybeal, J.D., Bott, R.H., Yoon, T., McGrath, B.E., and McGrath, J.E., Proc. of ACS Div. of Polym. Matls. Sci. Eng. 59, 934 (1988).Google Scholar
9. GmbH, Wacker-Chemie, product bulletin 3729, October 1988.Google Scholar