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Published online by Cambridge University Press: 01 February 2011
Photoluminescence (PL) spectra from Si nanocrystals embedded in silicon oxide matrix (Si-SiO2) thin films, Ge embedded in silicon oxide matrix (Ge-SiO2) thin films and both Ge and Si embedded in silicon oxide matrix (Ge/Si-SiO2) thin films prepared by RF magnetron sputtering were investigated. All as-deposited thin films were annealed for 1h in the temperature range from 500°C to 1100°C in Ar or H2 atmosphere. The PL spectra of Si-SiO2 thin films exhibited red luminescence at an annealing temperature of 1100°C and the PL intensity of the sample annealed in H2 gas increased by a factor of approximately 6.3 in comparison with sample annealed in Ar gas. Subsequently, The PL intensity of main peak centered at about 400 nm (V-band) of Ge-SiO2 thin films annealed in H2 gas exhibited strong comparison with the sample annealed in Ar gas. Finally, the PL spectra of Ge/Si-SiO2 thin films exhibited strong peak centered at approximately 500-530 nm (G-band) besides V-band and others in the temperature range from 700°C to 1000°C. The PL intensity of G-band of the samples annealed in H2 gas exhibited weak comparison with Ar gas.