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Phosphorus-Containing Poly (Arylene Ether)s as Second Order Nonlinear Optical Materials

Published online by Cambridge University Press:  16 February 2011

Duane B. Priddy Jr ,
C. Y. Stacey Fu ,
Timothy L. Pickering ,
Hilary S. Lackritz  and
James E. Mcgrath
Duane B. Priddy Jr
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and NSF Science and Technology Center: High Performance Polymeric Adhesives, Blacksburg, VA 24061–0344
C. Y. Stacey Fu
Affiliation:
Purdue University, School of Chemical Engineering, West Lafayette, Indiana 47907–1283
Timothy L. Pickering
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and NSF Science and Technology Center: High Performance Polymeric Adhesives, Blacksburg, VA 24061–0344
Hilary S. Lackritz
Affiliation:
Purdue University, School of Chemical Engineering, West Lafayette, Indiana 47907–1283
James E. Mcgrath*
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and NSF Science and Technology Center: High Performance Polymeric Adhesives, Blacksburg, VA 24061–0344
*
* To whom correspondence should be addressed
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Abstract

Poly (arylene ether)s can be designed to be amorphous, optically clear materials with excellent hydrolytic and thermal stability as well as good electrical, Mechanical and fire resistant properties. As a result, the use of these macromolecules in second order nonlinear optical (NLO) applications are being investigated. Typically, polymeric systems with doped chromophores result in a signigicant decrease in Tg. Methods were investigated to functionalize the polymer backbone with NLO chromophores, resulting in increased Tg.

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References

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