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Phase Selection During Interdiffusion in Ti-Fe Multilayered Films

Published online by Cambridge University Press:  21 February 2011

Z.Z. Yan ,
M.M. Trudeau ,
R. Schulz ,
R. Bormann ,
A.Van Neste  and
J.J. Ström-Olsen
Z.Z. Yan
Affiliation:
Hydro-Quebec Research Institute, Varennes, P.Q., Canada, J3X 151
M.M. Trudeau
Affiliation:
Hydro-Quebec Research Institute, Varennes, P.Q., Canada, J3X 151
R. Schulz
Affiliation:
Hydro-Quebec Research Institute, Varennes, P.Q., Canada, J3X 151
R. Bormann
Affiliation:
Institute for Materials Research, GKSS-Research Center, D-2054 Geesthacht, Germany
A.Van Neste
Affiliation:
Metallurgy Department, Laval University, P.Q., Canada, GIK 7P4
J.J. Ström-Olsen
Affiliation:
Centre for the Physics of Materials, McGill University, 3600 University Street, Montreal, P.Q., Canada, H3A 2T8
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Abstract

The formation of the metastable bcc solid solution and the amorphous phase during interfacial reaction of elemental multilayers has been studied using X-ray diffraction. Different kinds of interfaces have been synthesized in order to investigate the influence of the interfacial structure on phase evolution during annealing. The amorphization is found to be dependent on the structure of the interface and the results are discussed in terms of the kinetics and thermodynamics of the Ti-Fe system which has been calculated by the CALPHAD method.

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