Hostname: page-component-745bb68f8f-s22k5 Total loading time: 0 Render date: 2025-02-10T11:49:44.843Z Has data issue: false hasContentIssue false
  • English
  • Français

Optimization of the sintering of Aurivillius phases using D-optimal statistical design

Published online by Cambridge University Press:  11 February 2011

M.S. Peterson  and
S.T. Misture
M.S. Peterson
Affiliation:
New York State College of Ceramics at Alfred University, Alfred NY 14802
S.T. Misture
Affiliation:
New York State College of Ceramics at Alfred University, Alfred NY 14802
Get access

Abstract

A statistical model has been employed to determine the optimal sintering times and temperatures for Bi2Sr2Nb2TiO12. The phase of interest was made in pure form by solid-state synthesis. Bi2O3 was used as a sintering aid to decrease sintering temperatures and increase densification. The amount of Bi2O3 added and the sintering temperature had a statistical impact on density, while the heat treatment time did not.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 756: Symposia EE/FF – Solid-State Ionics – Materials for Fuel Cells and Fuel Processors , 2002 , FF4.8
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Aurivillius, B., “Mixed bismuth oxides with layer lattices: I. The structure type of CaNb2Bi2O9 ,” Arkiv for Kemi, 1 [54] 463–80 (1949).Google Scholar
2. Aurivillius, B., “Mixed bismuth oxides with layer lattices: II. Structure of Bi4Ti3O12 ,” Arkiv for Kemi, 1 [58] 499–512 (1949).Google Scholar
3. Aurivillius, B., “Mixed oxides with layer lattices: III. Structure of BaBi4Ti4O15 ,” Arkiv For Kemi, 2 [37] 519 (1950).Google Scholar
4. Rentschler, T., “Substitution of lead into the bismuth oxide layers of the n=2 and n=3 Aurivillius Phases,” Materials Research Bulletin, 32 [3] 351–69 (1997).Google Scholar
5. Peterson, M. S., Say, C. A., Speakman, S. A., and Misture, S. T., “High Temperature X-ray Diffraction Study of Reaction Rates of Ceramics,” Advances in X-ray Analysis, in review (2002).Google Scholar
6. Snedden, A., Blake, S. M., and Lightfoot, P., “Oxide ioin conductivity in Ga-doped Aurivillius phases- a reappraisal,” Solid State Ionics, Article in Press (2002).Google Scholar
7. Modi, V. B., “Electrical and microstructural characterization of N=3 type Aurivillius phases“; Thesis. New York State College of Ceramics at Alfred University, Alfred, 2002.Google Scholar
8. Lu, C.-H. and Chen, Y.-C., “Sintering and Decomposition of Ferroelectric Layer Perovskites: Strontium Bismuth Tantalate Ceramics,” Journal of the European Ceramic Society, 19 2909–15 (1999).Google Scholar
9. Experimental Design Optimizer, 1.0, Nextbridge Software, 1999.Google Scholar
10. ASTM Standards, “Standard test methods for apparent porosity, water absorbtion, apparent specific gravity, and bulk density of burned refractory brick and shapes by boiling water,” Refractories; Activated Carbon, Advanced Ceramics, C 20–97, Vol. 15.01. (2000).Google Scholar
11. Multiple Correlation Analysis, 1.0, Nextbridge Softwares, 1999.Google Scholar