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Optical Spectroscopy of a Nitrogen-Hydrogen Complex in ZnSe

Published online by Cambridge University Press:  22 February 2011

J. A. Wolk ,
J. W. Ager III ,
K. J. Duxstad ,
E. E. Haller ,
N. R. Taskar ,
D. R. Dorman  and
D. J. Olego
J. A. Wolk
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, California, 94720
J. W. Ager III
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, California, 94720
K. J. Duxstad
Affiliation:
Department of Materials Science and Mineral Engineering, University of California at Berkeley and Lawrence Berkeley Laboratory, Berkeley, California, 94720
E. E. Haller
Affiliation:
Department of Materials Science and Mineral Engineering, University of California at Berkeley and Lawrence Berkeley Laboratory, Berkeley, California, 94720
N. R. Taskar
Affiliation:
Philips Laboratories, Briarcliff Manor, New York, 10510
D. R. Dorman
Affiliation:
Philips Laboratories, Briarcliff Manor, New York, 10510
D. J. Olego
Affiliation:
Philips Laboratories, Briarcliff Manor, New York, 10510
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Abstract

We have observed two local vibrational modes related to H bonded to N acceptors in ZnSe samples grown by metal organic vapor phase epitaxy. The modes have been seen in both infrared and Raman spectroscopy. The new mode seen at 3194 cm-1 is assigned to an N-H stretching vibrational mode and the mode found at 783 cm-1 is tentatively assigned to an N-H wagging vibrational mode. Polarized Raman spectroscopy was used to determine that the symmetry of the defect complex is C3v, which implies that the H atom is in either a bonding or anti-bonding position.

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References

1 Mandel, G., Phys. Rev., 134, A 1073 (1964).Google Scholar
2 Laks, D. B., Walle, C. G. Van de, Neumark, G. F., and Pantelides, S. T., Phys. Rev. Lett., 66, 648 (1991).Google Scholar
3 Walukiewicz, W., to be published in Proceedings of the 1993 Spring Meeting of the Materials Research SocityGoogle Scholar
4 Qiu, J., Depuydt, J. M., Cheng, H., and Haase, M. A., Appl. Phys. Lett., 59, 2992 (1991).CrossRefGoogle Scholar
5 Taskar, N. R., Khan, B. A., Dorman, D. R., and Shahzad, K., Appl. Phys. Lett., 62, 270 (1993).Google Scholar
6 Fujita, Sz. and Fujita, Sg, J. Crystal Growth 117, 67 (1992).CrossRefGoogle Scholar
7 Yoshikava, A. and Okamoto, T., J. Crystal Growth 117, 107 (1992).Google Scholar
8 Chevalier, J., Clerjaud, B., and Pajot, B., in Semiconductors and Semimetals. eds. Pankove, J. I. and Johnson, N. M., (Academic Press, Inc., Boston, 1991), Vol.34, p. 447.Google Scholar
9 Clerjaud, B., Cote, D., Gendron, F., Hahn, W.-S., Krause, M., Porte, C., and Ulrici, W., in Proceedings of the 16th International Conference on Defects in Semiconductors, edited by Davies, G., Leo, G. G. De, and Stavola, M., (Trans Tech Publications, Switzerland, 1992), p.563.Google Scholar
10 Pajot, B., Song, C., and Porte, C., Proceedings of the 16th International Conference on Defects in Semiconductors, edited by Davies, G., Leo, G. G. De, and Stavola, M., (Trans Tech Publications, Switzerland, 1992), p.581.Google Scholar
11 In the notation [a(b,c)d], a (d) refers to the propagation vector of the incident (scattered) light, while b (c) refers to the polarization vector of the incident (scattered) light.Google Scholar
12 Cardona, M., in Light Scattering in Solids II, edited by Cardona, M. and Giintherodt, G., (Springer-Verlag, Berlin, 1982), p. 19.Google Scholar
13 Semiconductors and Semimetals, eds. Pankove, J. I. and Johnson, N. M., (Academic Press, Inc., Boston, 1991) Vol.34.Google Scholar
14 Clerjaud, B., Gendron, F., Krause, M., and Ulrici, W., Phys. Rev. Lett., 65, 1800 (1991).Google Scholar
15 Jones, R. and Öberg, S., Phys. Rev. B, 44, 3673 (1991).Google Scholar
16 Haukssan, I. S., Simpson, J., Wang, S. Y., Prior, K. A., and Cavenett, B. C., Appl. Phys. Lett. 61, 2208 (1992).Google Scholar