Hostname: page-component-54dcc4c588-m259h Total loading time: 0 Render date: 2025-09-12T10:31:24.161Z Has data issue: false hasContentIssue false
  • English
  • Français

Nonlinear Optical Properties of Chloronitroanilines

Published online by Cambridge University Press:  25 February 2011

D. J. Gerbi ,
G. T. Boyd ,
D. A. Ender  and
P. C. W. Leung
D. J. Gerbi
Affiliation:
Science Research Laboratory, 3M Co., St. Paul, MN 55144
G. T. Boyd
Affiliation:
Science Research Laboratory, 3M Co., St. Paul, MN 55144
D. A. Ender
Affiliation:
Science Research Laboratory, 3M Co., St. Paul, MN 55144
P. C. W. Leung
Affiliation:
Science Research Laboratory, 3M Co., St. Paul, MN 55144
Get access

Abstract

A series of chloronitroaniline compounds were investigated as bulk crystals and in thin film form as potential nonlinear optical materials for use in electro-optic devices. Crystal structure determination and computational modelling were completed on 5- chloro-2-nitroaniline and electro-optic measurements were performed on crystals grown by physical vapor deposition. Second harmonic generation measurements were carried out on poled guest/host systems of 3-chloro-4-nitroaniline in poly(methylmethacrylate).

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 109: Symposium K – Nonlinear Optical Properties of Polymers , 1987 , 331
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1. Williams, D. J., ed., Nonlinear Optical Properties of Organic and Polymeric Materials (American Chemical Society, Washington, D. C., 1985).Google Scholar
2. Gerbi, D. J., Leung, P. C. W. and Stofko, J. J., Patent Serial No. 84876 filed 13 Aug 1987.Google Scholar
3. Levine, B. F. and Bethea, C. G., J. Chem. Phys. 67, 446 (1977).Google Scholar
4. Bergman, J. and Crane, G. R., J. Chem. Phys. 66, 3803 (1977) and A. Corenco, J. Jerphagnon and A. Perigaud, J. Chem. Phys. 66, 3806 (1977).Google Scholar
5. Lipscomb, G. F., Garito, A. F., and Narang, R. S., J. Chem. Phys. 75, 1509 (1981).Google Scholar
6. Kurtz, S. K. and Perry, T. T., J. Appl. Phys. 39, 2798 (1969).Google Scholar
7. McPhil, A. T. and Sim, G. A., J. Chem. Soc. 1965, 227.CrossRefGoogle Scholar
8. Oudar, J. L. and Chemla, D. S., J. Chem. Phys. 66, 2664 (1977).Google Scholar
9. The molecular coordinate system, as shown in Figure 3, is defined such that the x-axis is along the vector joining the nitro- and amino- groups, and the y-axis is also on the molecular plane. The dipole moment coordinate system (x′,y′,z′) is also shown in Figure 3, in which x′ is parallel to the ground state dipole moment of the molecule. The crystal coordinate system (a,b,c) is shown in Figure 4. The optical axis system (X,Y,Z) is defined as X parallel to b; Y parallel to c and Z parallel to a.Google Scholar
10. Pople, J. A. and Segal, G. A. J. Chem. Phys. 44, 3289 (1966).Google Scholar
11. Turner, E. H., Appl. Phys. Lett. 8, 303 (1966).Google Scholar
12. Singer, K. D., Lalama, S. J., Sohn, J. E. and Small, R. D., Nonlinear Optical Properties of Organic Molecules and Crystals, vol 1, ed. by Chemla, D. S. and Zyss, J. (Academic Press, N. Y., 1987) p. 437.CrossRefGoogle Scholar