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Linear and Non-Linear Optical Properties of (2-Cyano-5-Methoxy-1,4-Phenylenevinylene) and Paraphenylenevinylene Copolymers

Published online by Cambridge University Press:  15 February 2011

Jang-Joo Kim ,
Do-Hoon Hwang ,
Shin-Woong Kang  and
Hong-Ku Shim
Jang-Joo Kim
Affiliation:
Electronics and Telecommunications Research Institute, P.O.Box 8, Daeduk Science Town, Daejeon, 305-606, KOREA
Do-Hoon Hwang
Affiliation:
Korea Advanced Institute of Science and Technology, Dept. of Chemistry, Daeduk Science Town, Daejeon, 305-701, KOREA
Shin-Woong Kang
Affiliation:
Korea Advanced Institute of Science and Technology, Dept. of Chemistry, Daeduk Science Town, Daejeon, 305-701, KOREA
Hong-Ku Shim
Affiliation:
Korea Advanced Institute of Science and Technology, Dept. of Chemistry, Daeduk Science Town, Daejeon, 305-701, KOREA
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Abstract

Poly(CMPV-co-PV) have been synthesized via water soluble sulfonium salt precursor route and their linear and non-linear optical properties were characterized. The electro-optic response was stable up to 100°C when the materials were poled during the elimination. The thermal stability and mechanical strength of PPV and its derivatives, and easy processibility from the precursor polymers suggest a new approach for the molecular design of the 2nd order non-linear optical polymers.

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References

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