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In Situ X-Ray Investigation of Novel Protonic Conductors

Published online by Cambridge University Press:  25 February 2011

Veniamin Sh. Shekhtman  and
Ruben A. Dilanyan
Veniamin Sh. Shekhtman
Affiliation:
Institute of Solid State Physics, Chernogolovka, Russia
Ruben A. Dilanyan
Affiliation:
Institute of Solid State Physics, Chernogolovka, Russia
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Abstract

Systematic X-ray diffraction studies of thermal expansion in CsHSO4, CsDSO4, RbHSO4 and Rb3H(SeO4)2 crystals have been carried out. An analysis of the results showed that the fast protonic conductivity is closely connected with the characteristic features of the structure, symmetry and orientation of hydrogens bonds in the crystals of MeXAO4 (Me=NI4, Rb, Cs; X= D,H; A= S,Se) family.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 293: Symposium U – Solid State Ionics III , 1992 , 453
Copyright
Copyright © Materials Research Society 1993

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References

1. Baranov, A.I., Phedosuk, R.M., Schagina, N.M., Shuvalov, L.A., Ferroelectrics Lett. 2, 25 (1984).Google Scholar
2. Baranov, A.I., Sov. J. Crist. 30, 682 (1987).Google Scholar
3. Itoh, K., Ukeda, T., Ozaki, T., Nakamura, E., Acta Cryst. C60, 358 (1990).Google Scholar
4. Merinov, B.V., Baranov, A.I., Maksimov, B.A., Shuvalov, L.A., Sov. J. Crist. 31, 450 (1986).Google Scholar
5. Ashmore, J.P., Petch, H.E., Can. J. Phys. 53, 2694 (1975).Google Scholar
6. Dilanyan, R.A., Shekctman, V.Sh., Baranov, A.I., Shuvaov, L.A., Sov. J. Solid St. Phys. 28, 587 (1986).Google Scholar
7. Merinov, B.V., Sov. J. Crist. 32, 86 (1987).Google Scholar
8. Baranov, A.I., Shuvalov, L.A., Schagina, N.M., Sov. J. Crist. 29, 1203 (1984).Google Scholar
9. Sinitsin, V.V., Baranov, A.I., Sov. J. Solid St. Phys 30, 2838 (1988).Google Scholar
10. Makarova, I.P., Verin, I.A., Schagina, N.M., Sov. J. Crist. 31, 178 (1986).Google Scholar
11. Dilanyan, R.A., Shekctman, V.Sh., Sov. J. Solid St. Phys. 29, 3577 (1987).Google Scholar
12. Dilanyan, R.A., Shekctman, V.Sh., Sov. J. Solid St. Phys. 31, 62 (1989).Google Scholar
13. Wooster, W.A., Tensors and group theory for the physical properties of crystals, (Oxford, 1973),Google Scholar
14. Aleksandrov, K.S., Kruglik, A.I., Misul, C.V., Simonov, M.A., Sov. J. Crist. 25, 1142 (1980).Google Scholar
15. Waskowska, A., Olejnik, S., Acta Cryst. B34, 3344 (1978).Google Scholar
16. Baran, J., Lis, T., Acta Cryst. C43, 811 (1987).Google Scholar
17. Nelmes, R.J., Acta Cryst. B27, 272 (1971).Google Scholar
18. Lushnikov, S.G., Siny, I.G., Ferroelectrics 106, 1073 (1990).Google Scholar
19. Dilanyan, R.A., Sinitsin, V.V., Shekctman, V.Sh., Baranov, A.I., Shuvalov, L.A., Sov. J. Solid St. Phys. (unpublished).Google Scholar