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In Situ X-Ray Diffraction and In Situ X-Ray Absorption Spectroscopy for Investigation of Intercalation Batteries: Application to the Alkaline H+/γ-MnO2 system.

Published online by Cambridge University Press:  28 February 2011

C. Lévy-Clèment ,
C. Mondoloni ,
C. Godart  and
R. Cortès
C. Lévy-Clèment
Affiliation:
Laboratoire de Physique des Solides de Bellevue, CNRS, 1, place A. Briand, 92195 MEUDON, FRANCE
C. Mondoloni
Affiliation:
Laboratoire de Physique des Solides de Bellevue, CNRS, 1, place A. Briand, 92195 MEUDON, FRANCE
C. Godart
Affiliation:
Laboratoire de Métallurgie des terres rares, CNRS, 1, place A. Briand 92195 MEUDON, FRANCE
R. Cortès
Affiliation:
LURE, 91405 ORSAY, FRANCE and Laboratoire d'Electrochimie et Phys. des liquides- Rue Vauquelin- 75005 PARIS, FRANCE
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Abstract

This paper presents applications of in situ X-ray diffraction and absorption techniques to the study of H+/MnO2 alkaline batteries. The two complementary in situ techniques are described. Investigation of the electrochemical insertion and deinsertion of H+ has been made through its influence on the evolution of the crystallographic structure of γ-MnO2, while investigation of the transfer of e has been undertaken through the variation of the oxidation state of the manganese during the discharging and charging process of a battery. New insights in the understanding of the mechanisms of proton insertion and charge transfer into γ-MnO2 are discussed.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 210: Symposium L – Solid State Ionics II , 1990 , 387
Copyright
Copyright © Materials Research Society 1991

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