Published online by Cambridge University Press: 01 February 2011
Hetero-epitaxy of crystalline perovskite SrTiO3 and BaTiO3 on GaAs(001) was achieved using molecular beam epitaxy. A number of surface and interface techniques were used to characterize the growth, structural, and chemical properties of epitaxial oxide films on GaAs. Reflection-high-energy-electron diffraction of SrTiO3 and BaTiO3 showed streaky diffraction features and low diffraction background through out growth, indicating that the epitaxial SrTiO3 and BaTiO3 films had good crystallinity. X-ray diffraction showed an epitaxial relationship between these perovskite oxides and GaAs(001) substrates. Transmission electron microscopy and scanning probe microscopy revealed an abrupt oxide/GaAs interface and smooth SrTiO3 and BaTiO3 surfaces. The success of growth of epitaxial perovskite oxides on GaAs enabled us to integrate a number of functional oxides such as piezoelectric and magnetic oxides epitaxially on GaAs substrates.