Hostname: page-component-745bb68f8f-hvd4g Total loading time: 0 Render date: 2025-02-04T15:51:57.797Z Has data issue: false hasContentIssue false
  • English
  • Français

The Formation of thin Films and Fibers of TiC from a Polymeric Titanate Precursor

Published online by Cambridge University Press:  28 February 2011

S-J. Ting ,
C-J. Chu ,
E. Limatta ,
J. D. Mackenzie ,
T. Getman  and
M. F. Hawthorne
S-J. Ting
Affiliation:
Department of Materials Science and Engineering and
C-J. Chu
Affiliation:
Department of Materials Science and Engineering and
E. Limatta
Affiliation:
Department of Materials Science and Engineering and
J. D. Mackenzie
Affiliation:
Department of Materials Science and Engineering and
T. Getman
Affiliation:
Department of Materials Science and Engineering and
M. F. Hawthorne
Affiliation:
Department of Chemistry and Biochemistry, University of California at Los Angeles, Los Angeles, CA 90024
Get access

Abstract

The synthesis and characterization of several polymeric titanates and their conversion to carbon deficient TiC is described. The physical properties of one of these titanates allows it to be drawn into fibers and applied to substrates as thin films. Pyrolysis of these fibers and films to carbon deficient TiC is described.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 180: Symposium A – Better Ceramics Through Chemistry IV , 1990 , 457
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Yajima, S.; Hayashi, J.; Omori, M. Chem. Lett., 931 (1975).Google Scholar
2. Yajima, S.; Okamura, K.; Hayashi, J.; Omori, M. J. Am. Chem. Soc., 59, 423 (1976).Google Scholar
3. Yajima, S.; Hasegawa, Y.; Okamura, K.; Matsuzawa, T. Nature, 273, 525, (1978).Google Scholar
4. Wynne, K. J.; Rice, R. W. Ann. Rev. Mat. Sci., 14, 297 (1984).Google Scholar
5. West, R. W.; “Ultrastructure Processing of Ceramics, Glasses and Composites,” Hench, L. L.; Ulrich, D. R.; (eds.), Wiley, NY, 19 (1984).Google Scholar
6. Yajima, S. Am. Ceram. Soc. Bull., 62, 893 (1983).Google Scholar
7. Willis, R. R.; Markle, R. A.; Mukherjee, S. P. Am. Ceram. Soc. Bull., 62, 904 (1983)Google Scholar
8. a) Bradley, D. C.; Mehrotra, R. C.; Gaur, D. P. “Metal Alkoxides,” Academic Press, New York (1978).Google Scholar
b) Bradley, D. C. Advan. Inorg. Chem. Radiochem., 15, 259 (1972).Google Scholar
9. Storm, E. K. “The Refractory Carbides,” Margrave, J. L., Ed., Acedemic Press, NY, Chapter 1 (1967)Google Scholar