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Facile One-Pot Synthesis of Rhenium Nanoparticles

Published online by Cambridge University Press:  23 September 2014

Tuğçe Ayvalı ,
Pierre Lecante ,
Pier-Francesco Fazzini ,
Angélique Gillet ,
Karine Philippot  and
Bruno Chaudret
Tuğçe Ayvalı
Affiliation:
CNRS ; LCC (Laboratoire de Chimie de Coordination) ; 205 Route de Narbonne ; F-31077 Toulouse (France) and UPS (Université de Toulouse), INPT, LCC ; F-31077 Toulouse (France)
Pierre Lecante
Affiliation:
CNRS UPR 8011; CEMES (Centre d’Elaboration des Matériaux et d’Etudes Structurales) 29 Rue Jeanne Marvig, 31055 Toulouse (France)
Pier-Francesco Fazzini
Affiliation:
LPCNO (Laboratoire de Physique et Chimie des Nano-Objets) ; UMR 5215 INSA-CNRS-UPS, Institut des Sciences Appliquées, 135 Avenue de Rangueil, F-31077 Toulouse (France)
Angélique Gillet
Affiliation:
LPCNO (Laboratoire de Physique et Chimie des Nano-Objets) ; UMR 5215 INSA-CNRS-UPS, Institut des Sciences Appliquées, 135 Avenue de Rangueil, F-31077 Toulouse (France)
Karine Philippot
Affiliation:
CNRS ; LCC (Laboratoire de Chimie de Coordination) ; 205 Route de Narbonne ; F-31077 Toulouse (France) and UPS (Université de Toulouse), INPT, LCC ; F-31077 Toulouse (France)
Bruno Chaudret
Affiliation:
LPCNO (Laboratoire de Physique et Chimie des Nano-Objets) ; UMR 5215 INSA-CNRS-UPS, Institut des Sciences Appliquées, 135 Avenue de Rangueil, F-31077 Toulouse (France)
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Abstract

This paper describes the organometallic synthesis of pure rhenium nanoparticles (Re NPs) and their characterization by a combination of state-of-the art techniques (TEM, HAADF-STEM, EDX, WAXS, EA, FT-IR). The Re NPs synthesis is achieved by reducing the [Re2(C3H5)4] complex in solution under a dihydrogen atmosphere and in the presence of hexadecylamine or polyvinylpyrrolidone as stabilizing agents. The so-obtained Re NPs are monodisperse with a mean size of 1.1 nm (0.3) nm and display a spherical shape with a disordered hcp structure.

Keywords

nanostructureResurface chemistry

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