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Facile Mechanochemical Synthesis and Magnetic Properties of pervoskite YCrxFe1-xO3, (0≤x≤1).

Published online by Cambridge University Press:  19 April 2012

Vijayalaxmi MalagaReddy ,
Binod Rai ,
Sanjay Mishra ,
Chaunbing Rong  and
J Liu
Vijayalaxmi MalagaReddy
Affiliation:
Department of Physics, The University of Memphis, Memphis, TN 38152
Binod Rai
Affiliation:
Department of Physics, The University of Memphis, Memphis, TN 38152
Sanjay Mishra
Affiliation:
Department of Physics, The University of Memphis, Memphis, TN 38152
Chaunbing Rong
Affiliation:
Department of Physics, The University of Texas, Arlington, TX
J Liu
Affiliation:
Department of Physics, The University of Texas, Arlington, TX
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Abstract

Single-phase samples of YCrxFe1−xO3 were synthesized by a mechanochemical method. X-ray diffraction data show linear reduction in the lattice parameters of YCrxFe1−xO3 perovskites with the Cr content, indicating that Cr ions substitute for Fe ions to form a solid solution. Magnetic measurements show hysteresis loops at 5K. The substitution of Cr for Fe enhances the magnetization for up to x=0.33 Cr doping level. For higher doping levels, 0.33<x<1, the system behaves as a frustrated system. At x=1, YCrO3 behaves as a week ferromagnet with TN ~140 K. The chloride salt based machenochemical method offers simple synthesis route for the synthesis of pure multiferroic compounds.

Keywords

magnetic propertiesreactive ball millingferroelectric
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1397: Symposium P – Ferroelectric and Multiferroic Materials , 2012 , mrsf11-1397-p13-01
Copyright
Copyright © Materials Research Society 2012

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