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The Effect of Quantum Well Structures on the Thermoelectric Figure of Merit

Published online by Cambridge University Press:  25 February 2011

L. D. Hicks  and
M. S. Dresselhaus
L. D. Hicks
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. S. Dresselhaus
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

Currently the materials with the highest thermoelectric figure of merit, Z, are Bi2Te3 alloys. Therefore these compounds are the best thermoelectric refrigeration elements. However, since the 1960's only slow progress has been made in enhancing Z, either in Bi2Te3 alloys or in other thermoelectric materials. So far, the materials used in applications have all been in bulk form. In this paper, it is proposed that it may be possible to increase Z of certain materials by preparing them in quantum well superlattice structures. Calculations have been done to investigate the potential for such an approach, and also to evaluate the effect of anisotropy on the figure of merit. The calculations show that layering has the potential to increase significantly the figure of merit of a highly anisotropic material like Bi2Te3, provided that the superlattice multilayers are made in a particular orientation. This result opens the possibility of using quantum well superlattice structures to enhance the performance of thermoelectric coolers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 281: Symposium D – Semiconductor Heterostructures for Photonic and Electronic Applications , 1992 , 821
Copyright
Copyright © Materials Research Society 1993

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References

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