Hostname: page-component-745bb68f8f-kw2vx Total loading time: 0 Render date: 2025-02-04T16:50:33.473Z Has data issue: false hasContentIssue false

Effect of Intermetallic Compounds on the Properties of Tantalum

Published online by Cambridge University Press:  25 February 2011

P. Kumar
Affiliation:
CPM Division, Cabot Corporation, County Line Road, Boyertown, PA 19512
C.E. Mosheim
Affiliation:
CPM Division, Cabot Corporation, County Line Road, Boyertown, PA 19512
C.A. Michaluk
Affiliation:
CPM Division, Cabot Corporation, County Line Road, Boyertown, PA 19512
Get access

Extract

While pure tantalum has excellent corrosion resistance and formability, its high temperature properties and thermal stability are marginal for some intended applications. Traditional approaches for improving these properties have been dispersion and solid solution strengthening. Modifications of properties via an intermetallic precipitation was not considered until recently.

Results of an on-going investigation on the processing and evaluation of silicidestrengthened tantalum are presented. Yttrium silicide-containing Tantalum samples were produced via the P/M method. Evaluation consisted of microstructural, mechanical, chemical and functional tests. Results were compared with those of commercially available tantalum. Intermetallics precipitates were found to be very potent in altering these properties.

While the preliminary results are encouraging, extensive functional testing is required to assure that there is no unexpected adverse effect.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Cardonne, S.M., Kumar, P., Michaluk, C.A. and Schwartz, H.D., “Tantalum and Its Alloys”, Advanced Materials and Processes, Sept. 1992 Google Scholar
2. “Tantalum, Columbium and Their Alloys”, Published by Cabot Corp., 1986 Google Scholar
3. Kumar, P., Moser, K.D. and Chatterjee, T.K., “The Effect of Microalloying with Silicon on the Properties of Tantalum”, J.of Metals, Vol. 41, No. 10, October 1989, pp. 5053.Google Scholar
4. Dieter, G. E., Mechanical Metallurgy, McGraw-Hill Book Co., 1987, pp. 188220.Google Scholar
5. Anton, D. L., Snow, D. B., Favrow, L. H. and Giamei, A. F., “Dispersion Strengthening of High Temperature Niobium Alloys”, Report No. R89-917437-3, pp. 2. Issued by United Technology Research Center, East Hartford, CT 06108. July 31, 1989 Final Report. Contract No. F49620-86-C-0053 for Air Force office of Scientific Research, Building 410, Bolling Air Force Base, Washington DC 20332.Google Scholar
6. Kusunoki, K., Sumino, K., Kawasaki, Y. and Yamazaki, Y., “Effect of Amount of Y and Oxide content on the Secondary Recrystallization Temperature of Nickel - Base SuperalloysMetallurgical Transactions A, Vol. 21A, March 1990, pp. 547.Google Scholar
7. Williams, D. M. and Smith, G. C., “A Study of Oxide Particles and Oxide-Matrix Interfaces in Copper” in Proceedings of a Symposium on “Oxide Dispersion Strengthening, Editors: Ansell, G. S., Copper, T. D. and Lenel, F. V.. Publ. by Gordon and Breach, 1968, pp. 509–36.Google Scholar
8. Michaluk, C.A., Gray, G.T. and Chatterjee, T., “The Effect of Oxygen, Grain Size and Strain Rate on the Mechancial Behavior of Forged P/M Tantalum”, P/M in Aerospace Defense, and Demanding Applications-1993, Metal Powder Industries Federation, 1993, p. 195204.Google Scholar
9. Kumar, P. and Mosheim, C.E., U. S. Patent No. 5,171,379, “Tantalum Base Alloys”Google Scholar
10. McMasters, O. D., Gschneidner, K. A., Kaldis, E., and Sampietro, G., “Hightemperature enthalpies and standard Gibbs free energies of formation of the europium cholcogenides: EuO, EuS, EuSe and EuTe.” J. Chem. Thermodynamics, Vol. 6, 1974, P. 845–57.Google Scholar
11. Miller, K. C., “Thermodynamic Data for Inorganic Sulphides, Selenides & TelluridesButterworth and Co., 88 Kingsway, London WC2B6AB, 1974 publication. ISBN 0-408-70537XGoogle Scholar
12. Gschneidner, K. A., and, N. Kippenhan McMasters, O. D., “Thermochemistry of the Rare Earth” Rare-Earth Information Center Institute for Atomic Research, Iowa State University, Ames, Iowa 50010, August 1973.Google Scholar
13. deBoer, F. R., Boom, R., Mattens, W. C. M., Miedema, A. R. and Niessen, A. K., “Cohesion in Metals”, North-Holland publication, 1988, pp. 545.Google Scholar