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Controlling the Properties of Bulk Metal Oxides at a MolecularLevel: Alkoxides Vs Carboxylates‐Alkoxides Routes

Published online by Cambridge University Press:  21 February 2011

Liliane G. Hubert‐pfalzgraf ,
Stephane Daniele ,
Souad Boulmaaz  and
Renee Papiernik
Liliane G. Hubert‐pfalzgraf
Affiliation:
Université de Nice Sophia‐Antipolis, Parc Valrose, 06108 NICE Cédex 2, France
Stephane Daniele
Affiliation:
Université de Nice Sophia‐Antipolis, Parc Valrose, 06108 NICE Cédex 2, France
Souad Boulmaaz
Affiliation:
Université de Nice Sophia‐Antipolis, Parc Valrose, 06108 NICE Cédex 2, France
Renee Papiernik
Affiliation:
Université de Nice Sophia‐Antipolis, Parc Valrose, 06108 NICE Cédex 2, France
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Abstract

The reactions between alkoxides and/or alkoxides and anhydrous acetates havebeen investigated for access to advanced multicomponent niobates ortitanates and with the aim to get insight into relationships between thenature of the initial precursors ‐ single or mixed‐metal derivatives,ligands (OAc or OR, R = Et, iPr),…‐ and the properties of the finalmaterial. Data are based on a variety of techniques: FT‐IR, multinuclear NMR (1H, 13C, 207Pb, 113Cd),X‐ray investigations on single crystals. Powders have been analyzed by TGA,SEM‐EDX, light scattering and XRD.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 21
Copyright
Copyright © Materials Research Society 1998

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References

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