Hostname: page-component-745bb68f8f-s22k5 Total loading time: 0 Render date: 2025-02-10T06:39:31.182Z Has data issue: false hasContentIssue false
  • English
  • Français

Comparative Study of the Sol-Gel and Metallo-Organic Decomposition (MOD) Processes for the Preparation of Inorganic Materials

Published online by Cambridge University Press:  25 February 2011

Gustavo R. Paz-Pujalt ,
W. Nie  and
C. Lurin
Gustavo R. Paz-Pujalt
Affiliation:
Corporate Research Laboratories, Eastman Kodak Company, Rochester, NY 14650–2011
W. Nie
Affiliation:
Laboratoire de Science des Materiaux, Kodak Pathé, Chalon-sur-Saône, 71100, France
C. Lurin
Affiliation:
Laboratoire de Science des Materiaux, Kodak Pathé, Chalon-sur-Saône, 71100, France
Get access

Abstract

Sol-Gel processing and Metallo-Organic Decomposition are contrasted from the thermodynamics and chemical reactivity points of view. Differences and similarities on precursor requirements, processing characteristics, processing intermediates, and product formation pathways are outlined. Some specific examples are presented and their reaction thermodynamics are compared. Some conclusions regarding thermo-dynamic versus kinetic control are drawn from these examples.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 193
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Brinker, C. J. and Scherer, G. W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, CA, 1990).Google Scholar
2. Mantese, J. V., Micheli, A. L., Hamdi, A. H., and Vest, R. W., MRS Bulletin 14(10), 48 (1989).CrossRefGoogle Scholar
3. Xu, J. J., Shaikh, A. S., and Vest, R. W., IEEE Trans. UFFC 36, 307 (1989).CrossRefGoogle Scholar
4. Agostinelli, J. A., Paz-Pujalt, G. R., and Mehrotra, A. K., Physica C 156, 208 (1988).CrossRefGoogle Scholar
5. Baes, C. F. and Messmer, R. E., The Hydrolysis of Cations (Wiley, New York, 1976).Google Scholar
6. Livage, L., Henry, M., and Sanchez, C., Progress in Solid State Chemistry 18, 183 (1988).CrossRefGoogle Scholar
7. Mehrotra, R. C. and Bohra, R., Metal Carboxylates (Academic Press, London, 1983).Google Scholar
8. Paz-Pujalt, G. R., in High Tc Superconductor Thin Films, edited by Correra, L. (Elsevier Science Publishers, Amsterdam, 1992).Google Scholar
9. Paz-Pujalt, G. R., Mehrotra, A. K., Ferranti, S., and Agostinelli, J. A., Solid State Ionics 32/33, 1179 (1989).CrossRefGoogle Scholar
10. Cotton, F. A. and Wilkinson, G., Advanced Inorganic Chemistry, 5th ed. (Wiley, New York, 1988), p. 545.Google Scholar
11. Lange's Handbook of Chemistry, 5th ed., edited by Dean, John A. (McGraw-Hill, New York, 1985).Google Scholar
12. Tochitsky, E. I. and Romanova, N. I., Thin Solid Films 110, 55–64 (1983).CrossRefGoogle Scholar
13. Bratsch, S., J. Chem. Educ. 65(10), 877 (1988).CrossRefGoogle Scholar
14. Paz-Pujalt, G. R., unpublished results.Google Scholar
15. Paz-Pujalt, G. R., Physiea c, 166, 1772 (1990).Google Scholar
16. Novrotsky, A., in Solid State Chemistry Techniques, edited by Cheetham, A. K. and Day, P. (Clarendon Press, Oxford, 1987).Google Scholar