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Chemical Modification of Carbon Materials with Sulfur Functionalities

Published online by Cambridge University Press:  01 February 2011

Takako Nakamura  and
Tsuguyori Ohana
Takako Nakamura
Affiliation:
takako-nakamura@aist.go.jp, National Institute of Advanced Industrial Science and Technology, Research Center for Advanced Carbon Materials, Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan
Tsuguyori Ohana
Affiliation:
t.ohana@aist.go.jp, National Institute of Advanced Industrial Science and Technology, Research Center for Advanced Carbon Materials, Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan
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Abstract

Photolysis of cyclic disulfides in the presence of carbon materials such as diamond films and single-walled carbon nanotubes led to a surface modification to introduce thioalkylthiol functional groups, confirming by means of Raman, X-ray photoelectron spectroscopy and mass spectrometer measurements. The results on the value of S/C ratio of sulfur-modified diamond films depends on irradiation time by monitoring with XPS. Through thioalkylthiol moieties, an attachment of gold nanoparticles using self-assembly process was performed on carbon materials surfaces.

Keywords

chemical reactionsurface reactiondiamond

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1039: Symposium P – Diamond Electronics–Fundamentals to Applications II , 2007 , 1039-P07-01
Copyright
Copyright © Materials Research Society 2008

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