Hostname: page-component-745bb68f8f-b6zl4 Total loading time: 0 Render date: 2025-01-28T23:55:26.200Z Has data issue: false hasContentIssue false
  • English
  • Français

The Bonding of Fluorinated and Hydrogenated Ethers to Metal Surfaces: A Surface Science Approach to Tribology

Published online by Cambridge University Press:  28 February 2011

M.M. Walczak ,
P.K. Leavitt  and
P.A. Thiel
M.M. Walczak
Affiliation:
Department of Chemistry and Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA
P.K. Leavitt
Affiliation:
Department of Chemistry and Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA
P.A. Thiel
Affiliation:
National Science Foundation Presidential Young Investigator (1985-1989) and Camille and Henry Dreyfus Foundation Teacher-Scholar (1986-1990)
Get access

Abstract

We report a surface science study of fluorinated and hydrogenated ethers adsorbed at a metal surface. Fluorinated ethers bond less strongly to ruthenium surfaces than the hydrogenated analogs, both for atomically-smooth and atomically-rough surfaces. For the hydrogenated ethers, 0.03 to 0.17 monolayers undergo decomposition, while fluorinated ethers do not decompose significantly.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 140: Symposium S – New Materials Approaches to Tribology: Theory and Applications , 1988 , 417
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Quinn, T.F.J., The Application of Modern Physical Techniques to Tribology, (Newnes-Butterworths, London, 1971), p.1–4.Google Scholar
2. For example, Buckley, D.H., ASLE Transactions, 13, 39 (1970); 17, 36 (1974).CrossRefGoogle Scholar
3. Anton, A.B., Avery, N.R., Toby, B.H., Weinberg, W.H., J. Am. Chem. Soc., 108, 684 (1986).CrossRefGoogle Scholar
4. Henderson, M.A., P.L. Radloff, White, J.M., Mims, C.A., J. Chem. Phys., 92, 4111 (1988).CrossRefGoogle Scholar
5. Henderson, M.A., Radloff, P.L., Greenlief, C.M., White, J.M., Mims, C.A., J. Chem. Phys., 92, 4120 (1988).CrossRefGoogle Scholar
6. Hrbek, J., dePaola, R.A., Hoffmann, F.M., J. Chem. Phys., 81, 2818 (1984).CrossRefGoogle Scholar
7. Avery, N.R., Toby, B.H., Anton, A.B., Weinberg, W.H., Surf. Sci., 122, L574 (1982).CrossRefGoogle Scholar
8. Anton, A.B., Parmenter, J.E., Weinberg, W.H., J. Am. Chem. Soc., 108, 1823 (1986).CrossRefGoogle Scholar
9. Luth, H., Rubloff, G.W., Grobman, W.D., Surf. Sci., 63, 325 (1977).CrossRefGoogle Scholar
10. Sexton, B.A., Hughes, A.E., Surf. Sci., 140, 227 (1984).CrossRefGoogle Scholar
11. Rendulic, K.D., Sexton, B.A., J. Catalysis, 78, 126 (1982).CrossRefGoogle Scholar
12. Walczak, M.M., Leavitt, P.K., Thiel, P.A., J. Am. Chem. Soc., 109, 5621 (1987).CrossRefGoogle Scholar
13. Walczak, M.M., Ph.D. Thesis, Iowa State Univ., Ames, Iowa, in preparation.Google Scholar
14. Walczak, M.M., Thiel, P.A., in preparation.Google Scholar
15. Leavitt, P.K., Thiel, P.A., to be published.Google Scholar
16. Redhead, P.A., Vacuum, 12, 203 (1962).CrossRefGoogle Scholar
17. Williams, E.D., Weinberg, W.H., Surf. Sci., 82, 93, (1979).CrossRefGoogle Scholar
18. Feulner, P., Menzel, D., Surf. Sci., 154, 465 (1985).CrossRefGoogle Scholar
19. Chou, M.Y., Chelikowsky, J.R., Phys. Rev. Lett., 59, 1737 (1985).CrossRefGoogle Scholar
20. Ku, R., Gjostein, N. A., Bonzel, H. P., Surf Sci. 64, 465 (1977).CrossRefGoogle Scholar
21. Thiel, P.A., Madey, T.E., Surf. Sci. Reports, 7, (1987).CrossRefGoogle Scholar
22. Madey, T.E., Yates, J.T. Jr., Surf. Sci., 76, 397 (1978).CrossRefGoogle Scholar
23. Hoffmann, F.M., Upton, T.H., J. Phys. Chem., 88, 6209 (1984).CrossRefGoogle Scholar
24. Mitchell, A.D., Cross, L.C., Eds., Tables of Interatomic Distances and Configurations in Molecules and Ions, (Burlington House, London, 1958).Google Scholar
25. Chambers, R.D., Fluorine in Organic Chemistry, (John Wiley and Sons, New York, 1973).Google Scholar
26. Vedeneyev, V.I., Gurv'ich, L.V., Kondrat'yev, V.N., Medvedev, V.A., Frankevich, Y.L., Bond Energies, Ionization Potentials and Electron Affinities, (Edward Arnold Ltd., London, 1966).Google Scholar
27. Stacey, M., Tatlow, J.C., Sharpe, A.G., Advances in Fluorine Chemistry, Vol. 2 (Butterworths, London, 1961).Google Scholar