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Synthesis conditions of ordered mesostructured boron nitride prepared from borazinic precursors and CMK-3 carbon template

Published online by Cambridge University Press:  15 February 2011

Philippe Dibandjo ,
Laurence Bois ,
Fernand Chassagneux ,
A. Vuillermoz  and
Philippe Miele
Philippe Dibandjo
Affiliation:
Laboratoire Multimatériaux et Interfaces, UMR 5615, Bat Berthollet, Université Claude Bernard, 43 Bd du 11 nov 1918, Villeurbanne, France.
Laurence Bois
Affiliation:
Laboratoire Multimatériaux et Interfaces, UMR 5615, Bat Berthollet, Université Claude Bernard, 43 Bd du 11 nov 1918, Villeurbanne, France.
Fernand Chassagneux
Affiliation:
Laboratoire Multimatériaux et Interfaces, UMR 5615, Bat Berthollet, Université Claude Bernard, 43 Bd du 11 nov 1918, Villeurbanne, France.
A. Vuillermoz
Affiliation:
LPMCN, UMR 5586, Bât. L. Brillouin, Université Claude Bernard, 43 Bd du 11 nov 1918, Villeurbanne, France.
Philippe Miele
Affiliation:
Laboratoire Multimatériaux et Interfaces, UMR 5615, Bat Berthollet, Université Claude Bernard, 43 Bd du 11 nov 1918, Villeurbanne, France.
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Abstract

The preparation of ordered mesoporous boron nitride by using borazinic precursors as boron nitride source (tri(methylamino)borazine (MAB) and tri(chloro)borazine TCB) and a mesoporous carbon CMK-3 as template is reported. A template elimination performed by hydrogenation allows to obtain an organized porous structure. The X-ray diffraction, TEM and pore size analysis show that the structure of the BN molecular sieves synthesized from CMK-3 consists in a 2D regular array of uniform mesopores of 3.4 nm in diameter.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 876: Symposium A – Nanoporous and Nanostructured Materials for Catalysis, Sensor and Gas Separation Applications , 2005 , R12.5
Copyright
Copyright © Materials Research Society 2005

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